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trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
In the title compound, [V(C(15)H(11)O(2))(2)O(CH(3)OH)]·2CH(3)OH, the V(IV) atom is coordinated by two 1,3-diphenylpropane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octahedral g...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588710/ https://www.ncbi.nlm.nih.gov/pubmed/23468675 http://dx.doi.org/10.1107/S1600536812044686 |
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author | Pretorius, Carla Venter, Johan A. Roodt, Andreas |
author_facet | Pretorius, Carla Venter, Johan A. Roodt, Andreas |
author_sort | Pretorius, Carla |
collection | PubMed |
description | In the title compound, [V(C(15)H(11)O(2))(2)O(CH(3)OH)]·2CH(3)OH, the V(IV) atom is coordinated by two 1,3-diphenylpropane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octahedral geometry is significantly distorted, with the V(IV) atom lying 0.330 (3) Å above the equatorial plane formed by the O atoms of the two β-diketonate ligands. In the crystal, O—H⋯O hydrogen bonds between the coordinating methanol group in the complex and the two methanol solvent molecules lead to the formation of polymeric chains along the c-axis direction. Weak C—H⋯O contacts are also observed. |
format | Online Article Text |
id | pubmed-3588710 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887102013-03-06 trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate Pretorius, Carla Venter, Johan A. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [V(C(15)H(11)O(2))(2)O(CH(3)OH)]·2CH(3)OH, the V(IV) atom is coordinated by two 1,3-diphenylpropane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octahedral geometry is significantly distorted, with the V(IV) atom lying 0.330 (3) Å above the equatorial plane formed by the O atoms of the two β-diketonate ligands. In the crystal, O—H⋯O hydrogen bonds between the coordinating methanol group in the complex and the two methanol solvent molecules lead to the formation of polymeric chains along the c-axis direction. Weak C—H⋯O contacts are also observed. International Union of Crystallography 2012-10-03 /pmc/articles/PMC3588710/ /pubmed/23468675 http://dx.doi.org/10.1107/S1600536812044686 Text en © Pretorius et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Pretorius, Carla Venter, Johan A. Roodt, Andreas trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate |
title |
trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate |
title_full |
trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate |
title_fullStr |
trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate |
title_full_unstemmed |
trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate |
title_short |
trans-Bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate |
title_sort | trans-bis(1,3-diphenylpropane-1,3-dionato)(methanol)oxidovanadium(iv) methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588710/ https://www.ncbi.nlm.nih.gov/pubmed/23468675 http://dx.doi.org/10.1107/S1600536812044686 |
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