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trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate

In the title compound, [V(C(15)H(11)O(2))(2)O(CH(3)OH)]·2CH(3)OH, the V(IV) atom is coordinated by two 1,3-diphenyl­propane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octa­hedral g...

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Detalles Bibliográficos
Autores principales: Pretorius, Carla, Venter, Johan A., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588710/
https://www.ncbi.nlm.nih.gov/pubmed/23468675
http://dx.doi.org/10.1107/S1600536812044686
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author Pretorius, Carla
Venter, Johan A.
Roodt, Andreas
author_facet Pretorius, Carla
Venter, Johan A.
Roodt, Andreas
author_sort Pretorius, Carla
collection PubMed
description In the title compound, [V(C(15)H(11)O(2))(2)O(CH(3)OH)]·2CH(3)OH, the V(IV) atom is coordinated by two 1,3-diphenyl­propane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octa­hedral geometry is significantly distorted, with the V(IV) atom lying 0.330 (3) Å above the equatorial plane formed by the O atoms of the two β-diketonate ligands. In the crystal, O—H⋯O hydrogen bonds between the coordinating methanol group in the complex and the two methanol solvent mol­ecules lead to the formation of polymeric chains along the c-axis direction. Weak C—H⋯O contacts are also observed.
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spelling pubmed-35887102013-03-06 trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate Pretorius, Carla Venter, Johan A. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [V(C(15)H(11)O(2))(2)O(CH(3)OH)]·2CH(3)OH, the V(IV) atom is coordinated by two 1,3-diphenyl­propane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octa­hedral geometry is significantly distorted, with the V(IV) atom lying 0.330 (3) Å above the equatorial plane formed by the O atoms of the two β-diketonate ligands. In the crystal, O—H⋯O hydrogen bonds between the coordinating methanol group in the complex and the two methanol solvent mol­ecules lead to the formation of polymeric chains along the c-axis direction. Weak C—H⋯O contacts are also observed. International Union of Crystallography 2012-10-03 /pmc/articles/PMC3588710/ /pubmed/23468675 http://dx.doi.org/10.1107/S1600536812044686 Text en © Pretorius et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pretorius, Carla
Venter, Johan A.
Roodt, Andreas
trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
title trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
title_full trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
title_fullStr trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
title_full_unstemmed trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
title_short trans-Bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate
title_sort trans-bis(1,3-diphenyl­propane-1,3-dionato)(methanol)oxidovanadium(iv) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588710/
https://www.ncbi.nlm.nih.gov/pubmed/23468675
http://dx.doi.org/10.1107/S1600536812044686
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