Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)

In the title iron(II) complex, [Fe(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe—N = 2.191 (5) and 2.215 (4) Å], one N atom from the N-[(diethyl­amino)­dimethyl­sil­yl]anilide ligand [Fe—N = 1.943 (4) Å] and a c...

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Detalles Bibliográficos
Autor principal: Chen, Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588711/
https://www.ncbi.nlm.nih.gov/pubmed/23468676
http://dx.doi.org/10.1107/S1600536812044741
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author Chen, Juan
author_facet Chen, Juan
author_sort Chen, Juan
collection PubMed
description In the title iron(II) complex, [Fe(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe—N = 2.191 (5) and 2.215 (4) Å], one N atom from the N-[(diethyl­amino)­dimethyl­sil­yl]anilide ligand [Fe—N = 1.943 (4) Å] and a chloride ligand [Fe—Cl = 2.2798 (16) Å] in a distorted tetra­hedral geometry. The N—Si—N angle is 113.9 (3)°. The crystal packing exhibits no short inter­molecular contacts.
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spelling pubmed-35887112013-03-06 Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II) Chen, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title iron(II) complex, [Fe(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe—N = 2.191 (5) and 2.215 (4) Å], one N atom from the N-[(diethyl­amino)­dimethyl­sil­yl]anilide ligand [Fe—N = 1.943 (4) Å] and a chloride ligand [Fe—Cl = 2.2798 (16) Å] in a distorted tetra­hedral geometry. The N—Si—N angle is 113.9 (3)°. The crystal packing exhibits no short inter­molecular contacts. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588711/ /pubmed/23468676 http://dx.doi.org/10.1107/S1600536812044741 Text en © Juan Chen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Juan
Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)
title Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)
title_full Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)
title_fullStr Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)
title_full_unstemmed Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)
title_short Chlorido{N-[(diethyl­amino)­dimethyl­sil­yl]anilido-κN}(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′)iron(II)
title_sort chlorido{n-[(diethyl­amino)­dimethyl­sil­yl]anilido-κn}(n,n,n′,n′-tetra­methyl­ethane-1,2-diamine-κ(2) n,n′)iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588711/
https://www.ncbi.nlm.nih.gov/pubmed/23468676
http://dx.doi.org/10.1107/S1600536812044741
work_keys_str_mv AT chenjuan chloridondiethylaminodimethylsilylanilidoknnnnntetramethylethane12diaminek2nnironii

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