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(η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate
The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one molecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment bein...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588713/ https://www.ncbi.nlm.nih.gov/pubmed/23468678 http://dx.doi.org/10.1107/S1600536812044674 |
Sumario: | The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one molecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an η(6)-benzene ligand [Ru—centroid = 1.6964 (6) Å], two chloride ligands with an average Ru—Cl bond length of 2.4138 (3) Å and a dicyclohexylphenylphosphane ligand [Ru—P = 2.3786 (3) Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C—H⋯Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and intermolecular C—H⋯π interactions resulting in a zigzag pattern in the [101] direction. |
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