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(η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate

The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one mol­ecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment bein...

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Autores principales: Muller, Alfred, Davis, Wade L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588713/
https://www.ncbi.nlm.nih.gov/pubmed/23468678
http://dx.doi.org/10.1107/S1600536812044674
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author Muller, Alfred
Davis, Wade L.
author_facet Muller, Alfred
Davis, Wade L.
author_sort Muller, Alfred
collection PubMed
description The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one mol­ecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an η(6)-benzene ligand [Ru—centroid = 1.6964 (6) Å], two chloride ligands with an average Ru—Cl bond length of 2.4138 (3) Å and a dicyclo­hexyl­phenyl­phosphane ligand [Ru—P = 2.3786 (3) Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C—H⋯Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and inter­molecular C—H⋯π inter­actions resulting in a zigzag pattern in the [101] direction.
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spelling pubmed-35887132013-03-06 (η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate Muller, Alfred Davis, Wade L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one mol­ecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an η(6)-benzene ligand [Ru—centroid = 1.6964 (6) Å], two chloride ligands with an average Ru—Cl bond length of 2.4138 (3) Å and a dicyclo­hexyl­phenyl­phosphane ligand [Ru—P = 2.3786 (3) Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C—H⋯Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and inter­molecular C—H⋯π inter­actions resulting in a zigzag pattern in the [101] direction. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588713/ /pubmed/23468678 http://dx.doi.org/10.1107/S1600536812044674 Text en © Muller and Davis 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muller, Alfred
Davis, Wade L.
(η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate
title (η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate
title_full (η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate
title_fullStr (η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate
title_full_unstemmed (η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate
title_short (η(6)-Benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(II) benzene sesquisolvate
title_sort (η(6)-benzene)­dichlorido(dicyclo­hexyl­phenyl­phosphane)ruthenium(ii) benzene sesquisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588713/
https://www.ncbi.nlm.nih.gov/pubmed/23468678
http://dx.doi.org/10.1107/S1600536812044674
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