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(η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate
The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one molecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment bein...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588713/ https://www.ncbi.nlm.nih.gov/pubmed/23468678 http://dx.doi.org/10.1107/S1600536812044674 |
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author | Muller, Alfred Davis, Wade L. |
author_facet | Muller, Alfred Davis, Wade L. |
author_sort | Muller, Alfred |
collection | PubMed |
description | The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one molecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an η(6)-benzene ligand [Ru—centroid = 1.6964 (6) Å], two chloride ligands with an average Ru—Cl bond length of 2.4138 (3) Å and a dicyclohexylphenylphosphane ligand [Ru—P = 2.3786 (3) Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C—H⋯Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and intermolecular C—H⋯π interactions resulting in a zigzag pattern in the [101] direction. |
format | Online Article Text |
id | pubmed-3588713 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887132013-03-06 (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate Muller, Alfred Davis, Wade L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [RuCl(2)(C(6)H(6))(C(18)H(27)P)]·1.5C(6)H(6), contains one molecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an η(6)-benzene ligand [Ru—centroid = 1.6964 (6) Å], two chloride ligands with an average Ru—Cl bond length of 2.4138 (3) Å and a dicyclohexylphenylphosphane ligand [Ru—P = 2.3786 (3) Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C—H⋯Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and intermolecular C—H⋯π interactions resulting in a zigzag pattern in the [101] direction. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588713/ /pubmed/23468678 http://dx.doi.org/10.1107/S1600536812044674 Text en © Muller and Davis 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Muller, Alfred Davis, Wade L. (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate |
title | (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate |
title_full | (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate |
title_fullStr | (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate |
title_full_unstemmed | (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate |
title_short | (η(6)-Benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(II) benzene sesquisolvate |
title_sort | (η(6)-benzene)dichlorido(dicyclohexylphenylphosphane)ruthenium(ii) benzene sesquisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588713/ https://www.ncbi.nlm.nih.gov/pubmed/23468678 http://dx.doi.org/10.1107/S1600536812044674 |
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