(Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)

In the title compound, [Rh(C(10)H(9)O(2))(CO)(2)], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0...

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Detalles Bibliográficos
Autores principales: Pretorius, Carla, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588716/
https://www.ncbi.nlm.nih.gov/pubmed/23468681
http://dx.doi.org/10.1107/S1600536812044893
Descripción
Sumario:In the title compound, [Rh(C(10)H(9)O(2))(CO)(2)], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0.017 Å. In the crystal, C—H⋯O inter­action is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic inter­actions [3.308 (3) and 3.461 (3) Å] between neighbouring Rh(I) atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction.

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