(Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)

In the title compound, [Rh(C(10)H(9)O(2))(CO)(2)], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0...

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Detalles Bibliográficos
Autores principales: Pretorius, Carla, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588716/
https://www.ncbi.nlm.nih.gov/pubmed/23468681
http://dx.doi.org/10.1107/S1600536812044893
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author Pretorius, Carla
Roodt, Andreas
author_facet Pretorius, Carla
Roodt, Andreas
author_sort Pretorius, Carla
collection PubMed
description In the title compound, [Rh(C(10)H(9)O(2))(CO)(2)], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0.017 Å. In the crystal, C—H⋯O inter­action is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic inter­actions [3.308 (3) and 3.461 (3) Å] between neighbouring Rh(I) atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction.
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spelling pubmed-35887162013-03-06 (Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I) Pretorius, Carla Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(10)H(9)O(2))(CO)(2)], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0.017 Å. In the crystal, C—H⋯O inter­action is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic inter­actions [3.308 (3) and 3.461 (3) Å] between neighbouring Rh(I) atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588716/ /pubmed/23468681 http://dx.doi.org/10.1107/S1600536812044893 Text en © Pretorius and Roodt 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pretorius, Carla
Roodt, Andreas
(Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)
title (Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)
title_full (Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)
title_fullStr (Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)
title_full_unstemmed (Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)
title_short (Benzoyl­acetonato-κ(2) O,O′)dicarbonyl­rhodium(I)
title_sort (benzoyl­acetonato-κ(2) o,o′)dicarbonyl­rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588716/
https://www.ncbi.nlm.nih.gov/pubmed/23468681
http://dx.doi.org/10.1107/S1600536812044893
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AT roodtandreas benzoylacetonatok2oodicarbonylrhodiumi

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