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Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]

The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation...

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Detalles Bibliográficos
Autores principales: Rinta, Heikki, Peuronen, Anssi, Lahtinen, Manu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588717/
https://www.ncbi.nlm.nih.gov/pubmed/23468682
http://dx.doi.org/10.1107/S1600536812044765
Descripción
Sumario:The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn(II) cation is coordinated by a single L ligand via the hy­droxy O atom and by five bromide ions, resulting in a distorted octa­hedral MnBr(5)O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn(II) atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn—(μ-Br)(2)—Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O—H⋯Br hydrogen bonds are present. The distance between adjacent Mn(II) atoms is 4.022 (1) Å.