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Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588717/ https://www.ncbi.nlm.nih.gov/pubmed/23468682 http://dx.doi.org/10.1107/S1600536812044765 |
Sumario: | The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn(II) cation is coordinated by a single L ligand via the hydroxy O atom and by five bromide ions, resulting in a distorted octahedral MnBr(5)O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn(II) atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn—(μ-Br)(2)—Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O—H⋯Br hydrogen bonds are present. The distance between adjacent Mn(II) atoms is 4.022 (1) Å. |
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