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Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]

The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation...

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Autores principales: Rinta, Heikki, Peuronen, Anssi, Lahtinen, Manu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588717/
https://www.ncbi.nlm.nih.gov/pubmed/23468682
http://dx.doi.org/10.1107/S1600536812044765
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author Rinta, Heikki
Peuronen, Anssi
Lahtinen, Manu
author_facet Rinta, Heikki
Peuronen, Anssi
Lahtinen, Manu
author_sort Rinta, Heikki
collection PubMed
description The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn(II) cation is coordinated by a single L ligand via the hy­droxy O atom and by five bromide ions, resulting in a distorted octa­hedral MnBr(5)O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn(II) atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn—(μ-Br)(2)—Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O—H⋯Br hydrogen bonds are present. The distance between adjacent Mn(II) atoms is 4.022 (1) Å.
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spelling pubmed-35887172013-03-06 Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)] Rinta, Heikki Peuronen, Anssi Lahtinen, Manu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn(II) cation is coordinated by a single L ligand via the hy­droxy O atom and by five bromide ions, resulting in a distorted octa­hedral MnBr(5)O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn(II) atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn—(μ-Br)(2)—Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O—H⋯Br hydrogen bonds are present. The distance between adjacent Mn(II) atoms is 4.022 (1) Å. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588717/ /pubmed/23468682 http://dx.doi.org/10.1107/S1600536812044765 Text en © Rinta et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rinta, Heikki
Peuronen, Anssi
Lahtinen, Manu
Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
title Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
title_full Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
title_fullStr Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
title_full_unstemmed Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
title_short Poly[[μ-N,N′-bis­(2-hy­droxy­eth­yl)-N,N,N′,N′-tetra­methyl­propane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
title_sort poly[[μ-n,n′-bis­(2-hy­droxy­eth­yl)-n,n,n′,n′-tetra­methyl­propane-1,3-diaminium-κ(2) o:o′]tetra-μ-bromido-dibromidodimanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588717/
https://www.ncbi.nlm.nih.gov/pubmed/23468682
http://dx.doi.org/10.1107/S1600536812044765
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