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Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588717/ https://www.ncbi.nlm.nih.gov/pubmed/23468682 http://dx.doi.org/10.1107/S1600536812044765 |
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author | Rinta, Heikki Peuronen, Anssi Lahtinen, Manu |
author_facet | Rinta, Heikki Peuronen, Anssi Lahtinen, Manu |
author_sort | Rinta, Heikki |
collection | PubMed |
description | The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn(II) cation is coordinated by a single L ligand via the hydroxy O atom and by five bromide ions, resulting in a distorted octahedral MnBr(5)O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn(II) atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn—(μ-Br)(2)—Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O—H⋯Br hydrogen bonds are present. The distance between adjacent Mn(II) atoms is 4.022 (1) Å. |
format | Online Article Text |
id | pubmed-3588717 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887172013-03-06 Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)] Rinta, Heikki Peuronen, Anssi Lahtinen, Manu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title three-dimensional coordination polymer, [Mn(2)Br(6)(C(11)H(28)N(2)O(2))](n), consists of one Mn(II) cation, half of a dicationic N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium ligand (L) (the other half being generated by a twofold rotation axis), and three bromide ions. The Mn(II) cation is coordinated by a single L ligand via the hydroxy O atom and by five bromide ions, resulting in a distorted octahedral MnBr(5)O coordination geometry. Four of the bromide ions are bridging to two adjacent Mn(II) atoms, thereby forming polymeric chains along the a and b axes. The L units act as links between neighbouring Mn—(μ-Br)(2)—Mn chains, also forming a polymeric continuum along the c axis, which completes the formation of a three-dimensional network. Classical O—H⋯Br hydrogen bonds are present. The distance between adjacent Mn(II) atoms is 4.022 (1) Å. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588717/ /pubmed/23468682 http://dx.doi.org/10.1107/S1600536812044765 Text en © Rinta et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rinta, Heikki Peuronen, Anssi Lahtinen, Manu Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)] |
title | Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2)
O:O′]tetra-μ-bromido-dibromidodimanganese(II)] |
title_full | Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2)
O:O′]tetra-μ-bromido-dibromidodimanganese(II)] |
title_fullStr | Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2)
O:O′]tetra-μ-bromido-dibromidodimanganese(II)] |
title_full_unstemmed | Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2)
O:O′]tetra-μ-bromido-dibromidodimanganese(II)] |
title_short | Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2)
O:O′]tetra-μ-bromido-dibromidodimanganese(II)] |
title_sort | poly[[μ-n,n′-bis(2-hydroxyethyl)-n,n,n′,n′-tetramethylpropane-1,3-diaminium-κ(2)
o:o′]tetra-μ-bromido-dibromidodimanganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588717/ https://www.ncbi.nlm.nih.gov/pubmed/23468682 http://dx.doi.org/10.1107/S1600536812044765 |
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