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(3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2) N (1),O (5))aqua[(pyridin-2-yl)methanamine-κ(2) N,N′]copper(II)
In the title compound, [Cu(C(7)H(6)N(2)O(3))(C(6)H(8)N(2))(H(2)O)], the Cu(II) ion is in a distorted square-pyramidal N(3)O(2) environment formed by two bidentate chelating ligands in the equatorial coordination sites and one water molecule in the apical direction. In the crystal, O—H⋯O, N—H⋯O and...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588718/ https://www.ncbi.nlm.nih.gov/pubmed/23468683 http://dx.doi.org/10.1107/S1600536812044959 |
| _version_ | 1782261621035368448 |
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| author | Malinkin, Sergey Pavlenko, Vadim A. Gumienna-Kontecka, Elzbieta Prisyazhnaya, Elena V. Iskenderov, Turganbay S. |
| author_facet | Malinkin, Sergey Pavlenko, Vadim A. Gumienna-Kontecka, Elzbieta Prisyazhnaya, Elena V. Iskenderov, Turganbay S. |
| author_sort | Malinkin, Sergey |
| collection | PubMed |
| description | In the title compound, [Cu(C(7)H(6)N(2)O(3))(C(6)H(8)N(2))(H(2)O)], the Cu(II) ion is in a distorted square-pyramidal N(3)O(2) environment formed by two bidentate chelating ligands in the equatorial coordination sites and one water molecule in the apical direction. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds link the complex molecules into a three-dimensional supramolecular network. |
| format | Online Article Text |
| id | pubmed-3588718 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887182013-03-06 (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2) N (1),O (5))aqua[(pyridin-2-yl)methanamine-κ(2) N,N′]copper(II) Malinkin, Sergey Pavlenko, Vadim A. Gumienna-Kontecka, Elzbieta Prisyazhnaya, Elena V. Iskenderov, Turganbay S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(6)N(2)O(3))(C(6)H(8)N(2))(H(2)O)], the Cu(II) ion is in a distorted square-pyramidal N(3)O(2) environment formed by two bidentate chelating ligands in the equatorial coordination sites and one water molecule in the apical direction. In the crystal, O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds link the complex molecules into a three-dimensional supramolecular network. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588718/ /pubmed/23468683 http://dx.doi.org/10.1107/S1600536812044959 Text en © Malinkin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Malinkin, Sergey Pavlenko, Vadim A. Gumienna-Kontecka, Elzbieta Prisyazhnaya, Elena V. Iskenderov, Turganbay S. (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2) N (1),O (5))aqua[(pyridin-2-yl)methanamine-κ(2) N,N′]copper(II) |
| title | (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2)
N
(1),O
(5))aqua[(pyridin-2-yl)methanamine-κ(2)
N,N′]copper(II) |
| title_full | (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2)
N
(1),O
(5))aqua[(pyridin-2-yl)methanamine-κ(2)
N,N′]copper(II) |
| title_fullStr | (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2)
N
(1),O
(5))aqua[(pyridin-2-yl)methanamine-κ(2)
N,N′]copper(II) |
| title_full_unstemmed | (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2)
N
(1),O
(5))aqua[(pyridin-2-yl)methanamine-κ(2)
N,N′]copper(II) |
| title_short | (3-Acetyl-5-carboxylato-4-methyl-1H-pyrazol-1-ido-κ(2)
N
(1),O
(5))aqua[(pyridin-2-yl)methanamine-κ(2)
N,N′]copper(II) |
| title_sort | (3-acetyl-5-carboxylato-4-methyl-1h-pyrazol-1-ido-κ(2)
n
(1),o
(5))aqua[(pyridin-2-yl)methanamine-κ(2)
n,n′]copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588718/ https://www.ncbi.nlm.nih.gov/pubmed/23468683 http://dx.doi.org/10.1107/S1600536812044959 |
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