Bis{bis­[2-(diisopropyl­phosphan­yl)phen­yl]phosphanido-κ(3) P,P′,P′′}chloridonickel(II)

In the title compound, [Ni(C(24)H(36)P(3))Cl], the Ni(II) atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bo...

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Detalles Bibliográficos
Autores principales: Tedesco, Consiglia, Lamberti, Marina, Mazzeo, Mina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588721/
https://www.ncbi.nlm.nih.gov/pubmed/23468686
http://dx.doi.org/10.1107/S1600536812044947
Descripción
Sumario:In the title compound, [Ni(C(24)H(36)P(3))Cl], the Ni(II) atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the Ni(II) atom, retaining a stereochemically active lone pair.

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