Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)

In the mol­ecule of the title compound, [CoBr(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 6-methyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, π–π stacking inter­actions between the pyridine rings...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Khazali, Fereydoon, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588722/
https://www.ncbi.nlm.nih.gov/pubmed/23468687
http://dx.doi.org/10.1107/S1600536812045230
Descripción
Sumario:In the mol­ecule of the title compound, [CoBr(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 6-methyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, π–π stacking inter­actions between the pyridine rings along the a-axis direction [centroid–centroid distance = 3.761 (7) Å] and C—H⋯Br hydrogen bonds in the bc plane together generate the three-dimensional packing.

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