Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)

In the mol­ecule of the title compound, [CoBr(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 6-methyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, π–π stacking inter­actions between the pyridine rings...

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Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Khazali, Fereydoon, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588722/
https://www.ncbi.nlm.nih.gov/pubmed/23468687
http://dx.doi.org/10.1107/S1600536812045230
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
author_sort Shirvan, Sadif A.
collection PubMed
description In the mol­ecule of the title compound, [CoBr(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 6-methyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, π–π stacking inter­actions between the pyridine rings along the a-axis direction [centroid–centroid distance = 3.761 (7) Å] and C—H⋯Br hydrogen bonds in the bc plane together generate the three-dimensional packing.
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spelling pubmed-35887222013-03-06 Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) Shirvan, Sadif A. Haydari Dezfuli, Sara Khazali, Fereydoon Borsalani, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [CoBr(2)(C(11)H(10)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 6-methyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, π–π stacking inter­actions between the pyridine rings along the a-axis direction [centroid–centroid distance = 3.761 (7) Å] and C—H⋯Br hydrogen bonds in the bc plane together generate the three-dimensional packing. International Union of Crystallography 2012-11-07 /pmc/articles/PMC3588722/ /pubmed/23468687 http://dx.doi.org/10.1107/S1600536812045230 Text en © Shirvan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_full Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_fullStr Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_full_unstemmed Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_short Dibromido(6-methyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_sort dibromido(6-methyl-2,2′-bipyridine-κ(2) n,n′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588722/
https://www.ncbi.nlm.nih.gov/pubmed/23468687
http://dx.doi.org/10.1107/S1600536812045230
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AT borsalaniali dibromido6methyl22bipyridinek2nncobaltii

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