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Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)

In the title compound, [Ni(C(9)H(7)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Ni(II) ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octa­hedral geometry. In the...

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Detalles Bibliográficos
Autores principales: Wang, Jun, Nie, Jian-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588723/
https://www.ncbi.nlm.nih.gov/pubmed/23468688
http://dx.doi.org/10.1107/S160053681204514X
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author Wang, Jun
Nie, Jian-Hua
author_facet Wang, Jun
Nie, Jian-Hua
author_sort Wang, Jun
collection PubMed
description In the title compound, [Ni(C(9)H(7)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Ni(II) ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octa­hedral geometry. In the L ligand, the acetate group deviates significantly from the benzimidazole plane, the C—C—C—O(coordinating) torsion angle being 34.2 (5)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional supra­molecular network parallel to the bc plane.
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spelling pubmed-35887232013-03-06 Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II) Wang, Jun Nie, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(7)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Ni(II) ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octa­hedral geometry. In the L ligand, the acetate group deviates significantly from the benzimidazole plane, the C—C—C—O(coordinating) torsion angle being 34.2 (5)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional supra­molecular network parallel to the bc plane. International Union of Crystallography 2012-11-07 /pmc/articles/PMC3588723/ /pubmed/23468688 http://dx.doi.org/10.1107/S160053681204514X Text en © Wang and Nie 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jun
Nie, Jian-Hua
Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)
title Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)
title_full Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)
title_fullStr Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)
title_full_unstemmed Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)
title_short Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis­(ethanol-κO)nickel(II)
title_sort bis[2-(1h-benzimidazol-2-yl)acetato-κ(2) n (3),o]bis­(ethanol-κo)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588723/
https://www.ncbi.nlm.nih.gov/pubmed/23468688
http://dx.doi.org/10.1107/S160053681204514X
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