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Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis(ethanol-κO)nickel(II)
In the title compound, [Ni(C(9)H(7)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Ni(II) ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octahedral geometry. In the...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588723/ https://www.ncbi.nlm.nih.gov/pubmed/23468688 http://dx.doi.org/10.1107/S160053681204514X |
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author | Wang, Jun Nie, Jian-Hua |
author_facet | Wang, Jun Nie, Jian-Hua |
author_sort | Wang, Jun |
collection | PubMed |
description | In the title compound, [Ni(C(9)H(7)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Ni(II) ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octahedral geometry. In the L ligand, the acetate group deviates significantly from the benzimidazole plane, the C—C—C—O(coordinating) torsion angle being 34.2 (5)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular network parallel to the bc plane. |
format | Online Article Text |
id | pubmed-3588723 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887232013-03-06 Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis(ethanol-κO)nickel(II) Wang, Jun Nie, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(7)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Ni(II) ion is situated on an inversion center and is coordinated by two N and two O atoms from two 2-(1H-benzimidazol-2-yl)acetate (L) ligands and by two O atoms from two ethanol ligands in a distorted octahedral geometry. In the L ligand, the acetate group deviates significantly from the benzimidazole plane, the C—C—C—O(coordinating) torsion angle being 34.2 (5)°. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a two-dimensional supramolecular network parallel to the bc plane. International Union of Crystallography 2012-11-07 /pmc/articles/PMC3588723/ /pubmed/23468688 http://dx.doi.org/10.1107/S160053681204514X Text en © Wang and Nie 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Jun Nie, Jian-Hua Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2) N (3),O]bis(ethanol-κO)nickel(II) |
title | Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2)
N
(3),O]bis(ethanol-κO)nickel(II) |
title_full | Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2)
N
(3),O]bis(ethanol-κO)nickel(II) |
title_fullStr | Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2)
N
(3),O]bis(ethanol-κO)nickel(II) |
title_full_unstemmed | Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2)
N
(3),O]bis(ethanol-κO)nickel(II) |
title_short | Bis[2-(1H-benzimidazol-2-yl)acetato-κ(2)
N
(3),O]bis(ethanol-κO)nickel(II) |
title_sort | bis[2-(1h-benzimidazol-2-yl)acetato-κ(2)
n
(3),o]bis(ethanol-κo)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588723/ https://www.ncbi.nlm.nih.gov/pubmed/23468688 http://dx.doi.org/10.1107/S160053681204514X |
work_keys_str_mv | AT wangjun bis21hbenzimidazol2ylacetatok2n3obisethanolkonickelii AT niejianhua bis21hbenzimidazol2ylacetatok2n3obisethanolkonickelii |