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Bis(μ-diisopropylhydoxylaminato)-κ(2) O:N;κ(2) O:O-bis[(diisopropylhydoxylaminato-κO)beryllium]
The title compound, [Be(2)(C(6)H(14)NO)(4)], was prepared from a solution of BeCl(2) in diethyl ether and two equivalents of O-lithiated N,N-diisopropylhydoxylamine. The molecular structure is composed of a dinuclear unit forming a central five-membered planar Be—O—Be—O—N ring (sum of internal...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588725/ https://www.ncbi.nlm.nih.gov/pubmed/23468690 http://dx.doi.org/10.1107/S1600536812045655 |
| _version_ | 1782261622653321216 |
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| author | Berger, Raphael Johann Friedrich Jana, Surajit Monkowius, Uwe Mitzel, Norbert Werner |
| author_facet | Berger, Raphael Johann Friedrich Jana, Surajit Monkowius, Uwe Mitzel, Norbert Werner |
| author_sort | Berger, Raphael Johann Friedrich |
| collection | PubMed |
| description | The title compound, [Be(2)(C(6)H(14)NO)(4)], was prepared from a solution of BeCl(2) in diethyl ether and two equivalents of O-lithiated N,N-diisopropylhydoxylamine. The molecular structure is composed of a dinuclear unit forming a central five-membered planar Be—O—Be—O—N ring (sum of internal angles = 540.0°; r.m.s. deviation from planarity = 0.0087 Å). Both Be atoms show the unusual coordination number of three, with one Be atom coordinated by three O atoms and the other by two O atoms and one N atom, both in distorted trigonal–planar environments. The Be—O distances are in the range 1.493 (5)–1.600 (5) Å and the Be—N distance is 1.741 (5) Å. |
| format | Online Article Text |
| id | pubmed-3588725 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887252013-03-06 Bis(μ-diisopropylhydoxylaminato)-κ(2) O:N;κ(2) O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] Berger, Raphael Johann Friedrich Jana, Surajit Monkowius, Uwe Mitzel, Norbert Werner Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Be(2)(C(6)H(14)NO)(4)], was prepared from a solution of BeCl(2) in diethyl ether and two equivalents of O-lithiated N,N-diisopropylhydoxylamine. The molecular structure is composed of a dinuclear unit forming a central five-membered planar Be—O—Be—O—N ring (sum of internal angles = 540.0°; r.m.s. deviation from planarity = 0.0087 Å). Both Be atoms show the unusual coordination number of three, with one Be atom coordinated by three O atoms and the other by two O atoms and one N atom, both in distorted trigonal–planar environments. The Be—O distances are in the range 1.493 (5)–1.600 (5) Å and the Be—N distance is 1.741 (5) Å. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588725/ /pubmed/23468690 http://dx.doi.org/10.1107/S1600536812045655 Text en © Berger et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Berger, Raphael Johann Friedrich Jana, Surajit Monkowius, Uwe Mitzel, Norbert Werner Bis(μ-diisopropylhydoxylaminato)-κ(2) O:N;κ(2) O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] |
| title | Bis(μ-diisopropylhydoxylaminato)-κ(2)
O:N;κ(2)
O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] |
| title_full | Bis(μ-diisopropylhydoxylaminato)-κ(2)
O:N;κ(2)
O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] |
| title_fullStr | Bis(μ-diisopropylhydoxylaminato)-κ(2)
O:N;κ(2)
O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] |
| title_full_unstemmed | Bis(μ-diisopropylhydoxylaminato)-κ(2)
O:N;κ(2)
O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] |
| title_short | Bis(μ-diisopropylhydoxylaminato)-κ(2)
O:N;κ(2)
O:O-bis[(diisopropylhydoxylaminato-κO)beryllium] |
| title_sort | bis(μ-diisopropylhydoxylaminato)-κ(2)
o:n;κ(2)
o:o-bis[(diisopropylhydoxylaminato-κo)beryllium] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588725/ https://www.ncbi.nlm.nih.gov/pubmed/23468690 http://dx.doi.org/10.1107/S1600536812045655 |
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