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catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]

In the title hydrated coordination polymer, {[Zn(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite [1-10] chain is formed by the linking of [Zn(C(10)H(8)N(2))(H(2)O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl­ate dianionic linkers. The Zn(2+) coordination geometry is a tr...

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Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Xu, Yue, Qin, Xiao-Lin, Yuan, Yong-Peng, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588728/
https://www.ncbi.nlm.nih.gov/pubmed/23468693
http://dx.doi.org/10.1107/S1600536812045503
Descripción
Sumario:In the title hydrated coordination polymer, {[Zn(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite [1-10] chain is formed by the linking of [Zn(C(10)H(8)N(2))(H(2)O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl­ate dianionic linkers. The Zn(2+) coordination geometry is a trigonal bipyramid, with one N atom (from 2,2′-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each Zn(II) atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water mol­ecules generate a layer motif parallel to (001).