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catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]

In the title hydrated coordination polymer, {[Zn(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite [1-10] chain is formed by the linking of [Zn(C(10)H(8)N(2))(H(2)O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl­ate dianionic linkers. The Zn(2+) coordination geometry is a tr...

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Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Xu, Yue, Qin, Xiao-Lin, Yuan, Yong-Peng, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588728/
https://www.ncbi.nlm.nih.gov/pubmed/23468693
http://dx.doi.org/10.1107/S1600536812045503
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author Li, Ya-Feng
Xu, Yue
Qin, Xiao-Lin
Yuan, Yong-Peng
Gao, Wen-Yuan
author_facet Li, Ya-Feng
Xu, Yue
Qin, Xiao-Lin
Yuan, Yong-Peng
Gao, Wen-Yuan
author_sort Li, Ya-Feng
collection PubMed
description In the title hydrated coordination polymer, {[Zn(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite [1-10] chain is formed by the linking of [Zn(C(10)H(8)N(2))(H(2)O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl­ate dianionic linkers. The Zn(2+) coordination geometry is a trigonal bipyramid, with one N atom (from 2,2′-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each Zn(II) atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water mol­ecules generate a layer motif parallel to (001).
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spelling pubmed-35887282013-03-06 catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate] Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated coordination polymer, {[Zn(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite [1-10] chain is formed by the linking of [Zn(C(10)H(8)N(2))(H(2)O)](2+) entities by bridging, monodentate furan-2,5-dicarboxyl­ate dianionic linkers. The Zn(2+) coordination geometry is a trigonal bipyramid, with one N atom (from 2,2′-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each Zn(II) atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water mol­ecules generate a layer motif parallel to (001). International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588728/ /pubmed/23468693 http://dx.doi.org/10.1107/S1600536812045503 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ya-Feng
Xu, Yue
Qin, Xiao-Lin
Yuan, Yong-Peng
Gao, Wen-Yuan
catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]
title catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]
title_full catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]
title_fullStr catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]
title_full_unstemmed catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]
title_short catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)] dihydrate]
title_sort catena-poly[[[aqua­(2,2′-bipyridine-κ(2) n,n′)zinc]-μ-furan-2,5-dicarboxyl­ato-κ(2) o (2):o (5)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588728/
https://www.ncbi.nlm.nih.gov/pubmed/23468693
http://dx.doi.org/10.1107/S1600536812045503
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