Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]

A trimethyl­phenyl­ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C(9)H(14)N)(2)[Mo(2)(C(2)O(4))(O(2))(4)O(2)], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with on...

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Detalles Bibliográficos
Autores principales: Oba, Ayaka, Hashimoto, Masato
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588729/
https://www.ncbi.nlm.nih.gov/pubmed/23468694
http://dx.doi.org/10.1107/S1600536812045850
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author Oba, Ayaka
Hashimoto, Masato
author_facet Oba, Ayaka
Hashimoto, Masato
author_sort Oba, Ayaka
collection PubMed
description A trimethyl­phenyl­ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C(9)H(14)N)(2)[Mo(2)(C(2)O(4))(O(2))(4)O(2)], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra­dentate bridging ligand and bridges between the diperoxidomolybdate units.
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spelling pubmed-35887292013-03-06 Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)] Oba, Ayaka Hashimoto, Masato Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A trimethyl­phenyl­ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C(9)H(14)N)(2)[Mo(2)(C(2)O(4))(O(2))(4)O(2)], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra­dentate bridging ligand and bridges between the diperoxidomolybdate units. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588729/ /pubmed/23468694 http://dx.doi.org/10.1107/S1600536812045850 Text en © Oba and Hashimoto 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oba, Ayaka
Hashimoto, Masato
Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]
title Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]
title_full Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]
title_fullStr Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]
title_full_unstemmed Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]
title_short Bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(VI)]
title_sort bis(trimethyl­phenyl­ammonium) μ-oxalato-bis­[oxidodiperoxido­molybdate(vi)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588729/
https://www.ncbi.nlm.nih.gov/pubmed/23468694
http://dx.doi.org/10.1107/S1600536812045850
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