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catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2) N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2) N:N]]
The title compound, [Na(2)(C(6)H(18)NSi(2))(2)(C(6)H(16)N(2))](n), was found to consist of dimeric [Na(NSiMe(3))(2)] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N′,N′-tetramethylethylenediamine ligands, which act in an...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588730/ https://www.ncbi.nlm.nih.gov/pubmed/23468695 http://dx.doi.org/10.1107/S1600536812045126 |
| _version_ | 1782261623783686144 |
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| author | Kennedy, Alan R. Mulvey, Robert E. O’Hara, Charles T. Robertson, Stuart D. Robertson, Gemma M. |
| author_facet | Kennedy, Alan R. Mulvey, Robert E. O’Hara, Charles T. Robertson, Stuart D. Robertson, Gemma M. |
| author_sort | Kennedy, Alan R. |
| collection | PubMed |
| description | The title compound, [Na(2)(C(6)H(18)NSi(2))(2)(C(6)H(16)N(2))](n), was found to consist of dimeric [Na(NSiMe(3))(2)] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N′,N′-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction. |
| format | Online Article Text |
| id | pubmed-3588730 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887302013-03-06 catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2) N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2) N:N]] Kennedy, Alan R. Mulvey, Robert E. O’Hara, Charles T. Robertson, Stuart D. Robertson, Gemma M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(2)(C(6)H(18)NSi(2))(2)(C(6)H(16)N(2))](n), was found to consist of dimeric [Na(NSiMe(3))(2)] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N′,N′-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588730/ /pubmed/23468695 http://dx.doi.org/10.1107/S1600536812045126 Text en © Kennedy et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kennedy, Alan R. Mulvey, Robert E. O’Hara, Charles T. Robertson, Stuart D. Robertson, Gemma M. catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2) N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2) N:N]] |
| title |
catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2)
N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2)
N:N]] |
| title_full |
catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2)
N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2)
N:N]] |
| title_fullStr |
catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2)
N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2)
N:N]] |
| title_full_unstemmed |
catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2)
N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2)
N:N]] |
| title_short |
catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2)
N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2)
N:N]] |
| title_sort | catena-poly[sodium-μ(2)-(n,n,n′,n′-tetramethylethane-1,2-diamine)-κ(2)
n:n′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2)
n:n]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588730/ https://www.ncbi.nlm.nih.gov/pubmed/23468695 http://dx.doi.org/10.1107/S1600536812045126 |
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