cis-Bis{(E)-2-[(2-fluoro­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}bis­(pyridine-κN)nickel(II)

The structure of the title compound, [Ni(C(13)H(9)FNO)(2)(C(5)H(5)N)(2)], consists of an Ni(II) atom on a crystallographic center of symmetry, octa­hedrally bonded through both the N and O atoms to two 2-[(2-fluoro­phen­yl)imino­meth­yl]phenolate (L) ligands, as well as two pyridine ligands. The F a...

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Detalles Bibliográficos
Autores principales: Souza, Marcela C. G., Ferreira, Leonardo da C., Comerlato, Nadia M., Ferreira, Glaucio B., Visentin, Lorenzo do Canto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588732/
https://www.ncbi.nlm.nih.gov/pubmed/23468697
http://dx.doi.org/10.1107/S1600536812045576
Descripción
Sumario:The structure of the title compound, [Ni(C(13)H(9)FNO)(2)(C(5)H(5)N)(2)], consists of an Ni(II) atom on a crystallographic center of symmetry, octa­hedrally bonded through both the N and O atoms to two 2-[(2-fluoro­phen­yl)imino­meth­yl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluoro­phenyl group around its external C—N bond.

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