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cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2) N,O}bis(pyridine-κN)nickel(II)
The structure of the title compound, [Ni(C(13)H(9)FNO)(2)(C(5)H(5)N)(2)], consists of an Ni(II) atom on a crystallographic center of symmetry, octahedrally bonded through both the N and O atoms to two 2-[(2-fluorophenyl)iminomethyl]phenolate (L) ligands, as well as two pyridine ligands. The F a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588732/ https://www.ncbi.nlm.nih.gov/pubmed/23468697 http://dx.doi.org/10.1107/S1600536812045576 |
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author | Souza, Marcela C. G. Ferreira, Leonardo da C. Comerlato, Nadia M. Ferreira, Glaucio B. Visentin, Lorenzo do Canto |
author_facet | Souza, Marcela C. G. Ferreira, Leonardo da C. Comerlato, Nadia M. Ferreira, Glaucio B. Visentin, Lorenzo do Canto |
author_sort | Souza, Marcela C. G. |
collection | PubMed |
description | The structure of the title compound, [Ni(C(13)H(9)FNO)(2)(C(5)H(5)N)(2)], consists of an Ni(II) atom on a crystallographic center of symmetry, octahedrally bonded through both the N and O atoms to two 2-[(2-fluorophenyl)iminomethyl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluorophenyl group around its external C—N bond. |
format | Online Article Text |
id | pubmed-3588732 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887322013-03-06 cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2) N,O}bis(pyridine-κN)nickel(II) Souza, Marcela C. G. Ferreira, Leonardo da C. Comerlato, Nadia M. Ferreira, Glaucio B. Visentin, Lorenzo do Canto Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Ni(C(13)H(9)FNO)(2)(C(5)H(5)N)(2)], consists of an Ni(II) atom on a crystallographic center of symmetry, octahedrally bonded through both the N and O atoms to two 2-[(2-fluorophenyl)iminomethyl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluorophenyl group around its external C—N bond. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588732/ /pubmed/23468697 http://dx.doi.org/10.1107/S1600536812045576 Text en © Souza et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Souza, Marcela C. G. Ferreira, Leonardo da C. Comerlato, Nadia M. Ferreira, Glaucio B. Visentin, Lorenzo do Canto cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2) N,O}bis(pyridine-κN)nickel(II) |
title |
cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2)
N,O}bis(pyridine-κN)nickel(II)
|
title_full |
cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2)
N,O}bis(pyridine-κN)nickel(II)
|
title_fullStr |
cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2)
N,O}bis(pyridine-κN)nickel(II)
|
title_full_unstemmed |
cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2)
N,O}bis(pyridine-κN)nickel(II)
|
title_short |
cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2)
N,O}bis(pyridine-κN)nickel(II)
|
title_sort | cis-bis{(e)-2-[(2-fluorophenyl)iminomethyl]phenolato-κ(2)
n,o}bis(pyridine-κn)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588732/ https://www.ncbi.nlm.nih.gov/pubmed/23468697 http://dx.doi.org/10.1107/S1600536812045576 |
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