Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]

The title compound, [Cd(2)Br(4)(C(24)H(16)N(2))(2)], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for t...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Khazali, Fereydoon, Aghajeri, Manouchehr, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588733/
https://www.ncbi.nlm.nih.gov/pubmed/23468698
http://dx.doi.org/10.1107/S1600536812045928
Descripción
Sumario:The title compound, [Cd(2)Br(4)(C(24)H(16)N(2))(2)], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the Cd(II) atom. In the crystal, C—H⋯Br hydrogen bonds and π–π contacts between the pyridine and phenyl rings [centroid–centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supra­molecular structure.

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