Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]

The title compound, [Cd(2)Br(4)(C(24)H(16)N(2))(2)], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for t...

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Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Khazali, Fereydoon, Aghajeri, Manouchehr, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588733/
https://www.ncbi.nlm.nih.gov/pubmed/23468698
http://dx.doi.org/10.1107/S1600536812045928
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
author_sort Shirvan, Sadif A.
collection PubMed
description The title compound, [Cd(2)Br(4)(C(24)H(16)N(2))(2)], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the Cd(II) atom. In the crystal, C—H⋯Br hydrogen bonds and π–π contacts between the pyridine and phenyl rings [centroid–centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supra­molecular structure.
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spelling pubmed-35887332013-03-06 Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium] Shirvan, Sadif A. Haydari Dezfuli, Sara Khazali, Fereydoon Aghajeri, Manouchehr Borsalani, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)Br(4)(C(24)H(16)N(2))(2)], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the Cd(II) atom. In the crystal, C—H⋯Br hydrogen bonds and π–π contacts between the pyridine and phenyl rings [centroid–centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supra­molecular structure. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588733/ /pubmed/23468698 http://dx.doi.org/10.1107/S1600536812045928 Text en © Shirvan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]
title Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]
title_full Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]
title_fullStr Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]
title_full_unstemmed Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]
title_short Di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)cadmium]
title_sort di-μ-bromido-bis­[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) n,n′)cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588733/
https://www.ncbi.nlm.nih.gov/pubmed/23468698
http://dx.doi.org/10.1107/S1600536812045928
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