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[Aquabis(nitrato-κO)copper(II)]-μ-{bis[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua(nitrato-κO)copper(II)] nitrate monohydrate
In the title binuclear complex, [Cu(2)(NO(3))(3)(C(18)H(16)N(6)Se)(H(2)O)(3)]NO(3)·H(2)O, the Cu(II) ions are pentacoordinated in a tetragonal–pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water molecule and a nitrate O atom, whereas...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588734/ https://www.ncbi.nlm.nih.gov/pubmed/23468699 http://dx.doi.org/10.1107/S1600536812045217 |
Sumario: | In the title binuclear complex, [Cu(2)(NO(3))(3)(C(18)H(16)N(6)Se)(H(2)O)(3)]NO(3)·H(2)O, the Cu(II) ions are pentacoordinated in a tetragonal–pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water molecule and a nitrate O atom, whereas the apical positions are occupied by a water molecule for one Cu(II) ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C–Se–C plane. Numerous intermolecular O—H⋯O and N—H⋯O hydrogen bonds between the coordinating and lattice water molecules, nitrate anions and pyrazole groups are observed. π–π stacking interactions between the pyridine rings [averaged centroid–centroid distance = 3.652 (5) Å] are also present. The lattice water molecule is equally disordered over two sets of sites. |
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