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[Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate

In the title binuclear complex, [Cu(2)(NO(3))(3)(C(18)H(16)N(6)Se)(H(2)O)(3)]NO(3)·H(2)O, the Cu(II) ions are penta­coordinated in a tetra­gonal–pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water mol­ecule and a nitrate O atom, whereas...

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Autores principales: Seredyuk, Maksym, Pavlenko, Vadim A., Gumienna-Kontecka, Elzbieta, Iskenderov, Turganbay S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588734/
https://www.ncbi.nlm.nih.gov/pubmed/23468699
http://dx.doi.org/10.1107/S1600536812045217
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author Seredyuk, Maksym
Pavlenko, Vadim A.
Gumienna-Kontecka, Elzbieta
Iskenderov, Turganbay S.
author_facet Seredyuk, Maksym
Pavlenko, Vadim A.
Gumienna-Kontecka, Elzbieta
Iskenderov, Turganbay S.
author_sort Seredyuk, Maksym
collection PubMed
description In the title binuclear complex, [Cu(2)(NO(3))(3)(C(18)H(16)N(6)Se)(H(2)O)(3)]NO(3)·H(2)O, the Cu(II) ions are penta­coordinated in a tetra­gonal–pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water mol­ecule and a nitrate O atom, whereas the apical positions are occupied by a water mol­ecule for one Cu(II) ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C–Se–C plane. Numerous inter­molecular O—H⋯O and N—H⋯O hydrogen bonds between the coordinating and lattice water mol­ecules, nitrate anions and pyrazole groups are observed. π–π stacking inter­actions between the pyridine rings [averaged centroid–centroid distance = 3.652 (5) Å] are also present. The lattice water molecule is equally disordered over two sets of sites.
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spelling pubmed-35887342013-03-06 [Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate Seredyuk, Maksym Pavlenko, Vadim A. Gumienna-Kontecka, Elzbieta Iskenderov, Turganbay S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear complex, [Cu(2)(NO(3))(3)(C(18)H(16)N(6)Se)(H(2)O)(3)]NO(3)·H(2)O, the Cu(II) ions are penta­coordinated in a tetra­gonal–pyramidal geometry. In both cases, the equatorial planes are formed by a chelating pyrazole-pyridine group, a water mol­ecule and a nitrate O atom, whereas the apical positions are occupied by a water mol­ecule for one Cu(II) ion and a nitrate O atom for the other. The organic selenide ligand adopts a trans configuration with respect to the C–Se–C plane. Numerous inter­molecular O—H⋯O and N—H⋯O hydrogen bonds between the coordinating and lattice water mol­ecules, nitrate anions and pyrazole groups are observed. π–π stacking inter­actions between the pyridine rings [averaged centroid–centroid distance = 3.652 (5) Å] are also present. The lattice water molecule is equally disordered over two sets of sites. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588734/ /pubmed/23468699 http://dx.doi.org/10.1107/S1600536812045217 Text en © Seredyuk et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seredyuk, Maksym
Pavlenko, Vadim A.
Gumienna-Kontecka, Elzbieta
Iskenderov, Turganbay S.
[Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate
title [Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate
title_full [Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate
title_fullStr [Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate
title_full_unstemmed [Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate
title_short [Aqua­bis­(nitrato-κO)copper(II)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κO)copper(II)] nitrate monohydrate
title_sort [aqua­bis­(nitrato-κo)copper(ii)]-μ-{bis­[5-methyl-3-(pyridin-2-yl)-1h-pyrazol-4-yl]selenide}-[diaqua­(nitrato-κo)copper(ii)] nitrate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588734/
https://www.ncbi.nlm.nih.gov/pubmed/23468699
http://dx.doi.org/10.1107/S1600536812045217
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