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Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
In the heterometallic title bulky amido complex, [LiNa(C(15)H(21)N(2)Si)(2)(C(6)H(16)N(2))], both alkali metal ions are four-coordinated with distorted tetrahedral geometries. The Li(+) ion is N,N′-chelated by the N-silylated amido ligand, with Li—N = 2.015 (5) and 2.074 (5) Å. The two amido ligand...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588735/ https://www.ncbi.nlm.nih.gov/pubmed/23468700 http://dx.doi.org/10.1107/S160053681204576X |
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author | Chen, Juan Yuan, Li |
author_facet | Chen, Juan Yuan, Li |
author_sort | Chen, Juan |
collection | PubMed |
description | In the heterometallic title bulky amido complex, [LiNa(C(15)H(21)N(2)Si)(2)(C(6)H(16)N(2))], both alkali metal ions are four-coordinated with distorted tetrahedral geometries. The Li(+) ion is N,N′-chelated by the N-silylated amido ligand, with Li—N = 2.015 (5) and 2.074 (5) Å. The two amido ligands are arranged cis to each other. The molecule exhibits a twofold rotational symmetry operation along the Li–Na axis. The Na(+) ion is coordinated by two N atoms from the tetramethylethylenediamine ligand [Na—N = 2.553 (4) Å] and shares two amido N atoms from the N-silylated amido ligands with the Li(+) ion. Although the crystal structure contains voids with an approximate volume of 50 Å(3) there is no inclusion of solvent molecules. |
format | Online Article Text |
id | pubmed-3588735 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887352013-03-06 Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2) N,N′)lithiumsodium Chen, Juan Yuan, Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heterometallic title bulky amido complex, [LiNa(C(15)H(21)N(2)Si)(2)(C(6)H(16)N(2))], both alkali metal ions are four-coordinated with distorted tetrahedral geometries. The Li(+) ion is N,N′-chelated by the N-silylated amido ligand, with Li—N = 2.015 (5) and 2.074 (5) Å. The two amido ligands are arranged cis to each other. The molecule exhibits a twofold rotational symmetry operation along the Li–Na axis. The Na(+) ion is coordinated by two N atoms from the tetramethylethylenediamine ligand [Na—N = 2.553 (4) Å] and shares two amido N atoms from the N-silylated amido ligands with the Li(+) ion. Although the crystal structure contains voids with an approximate volume of 50 Å(3) there is no inclusion of solvent molecules. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588735/ /pubmed/23468700 http://dx.doi.org/10.1107/S160053681204576X Text en © Chen and Yuan 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Juan Yuan, Li Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2) N,N′)lithiumsodium |
title | Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2)
N
(1),N
(8):N
(8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2)
N,N′)lithiumsodium |
title_full | Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2)
N
(1),N
(8):N
(8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2)
N,N′)lithiumsodium |
title_fullStr | Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2)
N
(1),N
(8):N
(8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2)
N,N′)lithiumsodium |
title_full_unstemmed | Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2)
N
(1),N
(8):N
(8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2)
N,N′)lithiumsodium |
title_short | Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2)
N
(1),N
(8):N
(8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2)
N,N′)lithiumsodium |
title_sort | bis[μ-n-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2)
n
(1),n
(8):n
(8)](n,n,n′,n′-tetramethylethane-1,2-diamine-1κ(2)
n,n′)lithiumsodium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588735/ https://www.ncbi.nlm.nih.gov/pubmed/23468700 http://dx.doi.org/10.1107/S160053681204576X |
work_keys_str_mv | AT chenjuan bismntertbutyldimethylsilylquinolin8aminato12k2n1n8n8nnnntetramethylethane12diamine1k2nnlithiumsodium AT yuanli bismntertbutyldimethylsilylquinolin8aminato12k2n1n8n8nnnntetramethylethane12diamine1k2nnlithiumsodium |