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Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium

In the heterometallic title bulky amido complex, [LiNa(C(15)H(21)N(2)Si)(2)(C(6)H(16)N(2))], both alkali metal ions are four-coordinated with distorted tetra­hedral geometries. The Li(+) ion is N,N′-chelated by the N-silylated amido ligand, with Li—N = 2.015 (5) and 2.074 (5) Å. The two amido ligand...

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Autores principales: Chen, Juan, Yuan, Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588735/
https://www.ncbi.nlm.nih.gov/pubmed/23468700
http://dx.doi.org/10.1107/S160053681204576X
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author Chen, Juan
Yuan, Li
author_facet Chen, Juan
Yuan, Li
author_sort Chen, Juan
collection PubMed
description In the heterometallic title bulky amido complex, [LiNa(C(15)H(21)N(2)Si)(2)(C(6)H(16)N(2))], both alkali metal ions are four-coordinated with distorted tetra­hedral geometries. The Li(+) ion is N,N′-chelated by the N-silylated amido ligand, with Li—N = 2.015 (5) and 2.074 (5) Å. The two amido ligands are arranged cis to each other. The mol­ecule exhibits a twofold rotational symmetry operation along the Li–Na axis. The Na(+) ion is coordinated by two N atoms from the tetra­methyl­ethylenediamine ligand [Na—N = 2.553 (4) Å] and shares two amido N atoms from the N-silylated amido ligands with the Li(+) ion. Although the crystal structure contains voids with an approximate volume of 50 Å(3) there is no inclusion of solvent mol­ecules.
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spelling pubmed-35887352013-03-06 Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium Chen, Juan Yuan, Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heterometallic title bulky amido complex, [LiNa(C(15)H(21)N(2)Si)(2)(C(6)H(16)N(2))], both alkali metal ions are four-coordinated with distorted tetra­hedral geometries. The Li(+) ion is N,N′-chelated by the N-silylated amido ligand, with Li—N = 2.015 (5) and 2.074 (5) Å. The two amido ligands are arranged cis to each other. The mol­ecule exhibits a twofold rotational symmetry operation along the Li–Na axis. The Na(+) ion is coordinated by two N atoms from the tetra­methyl­ethylenediamine ligand [Na—N = 2.553 (4) Å] and shares two amido N atoms from the N-silylated amido ligands with the Li(+) ion. Although the crystal structure contains voids with an approximate volume of 50 Å(3) there is no inclusion of solvent mol­ecules. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588735/ /pubmed/23468700 http://dx.doi.org/10.1107/S160053681204576X Text en © Chen and Yuan 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Juan
Yuan, Li
Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
title Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
title_full Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
title_fullStr Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
title_full_unstemmed Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
title_short Bis[μ-N-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
title_sort bis[μ-n-(tert-butyl­dimethyl­sil­yl)quinolin-8-aminato-1:2κ(2) n (1),n (8):n (8)](n,n,n′,n′-tetra­methyl­ethane-1,2-diamine-1κ(2) n,n′)lithiumsodium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588735/
https://www.ncbi.nlm.nih.gov/pubmed/23468700
http://dx.doi.org/10.1107/S160053681204576X
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