trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate

In the title compound, [PtCl(2)(C(21)H(21)O(3)P)(2)]·2C(3)H(6)O, the asymmetric unit contains a Pt(II) ion situated on an inversion center, one chloride anion, one tris­(4-meth­oxy­lphen­yl)phosphane (L) ligand and one acetone solvent mol­ecule. The Pt(II) ion is coordinated by two P atoms [Pt—P = 2...

Descripción completa

Detalles Bibliográficos
Autor principal: Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588736/
https://www.ncbi.nlm.nih.gov/pubmed/23468701
http://dx.doi.org/10.1107/S1600536812045643
_version_ 1782261625159417856
author Muller, Alfred
author_facet Muller, Alfred
author_sort Muller, Alfred
collection PubMed
description In the title compound, [PtCl(2)(C(21)H(21)O(3)P)(2)]·2C(3)H(6)O, the asymmetric unit contains a Pt(II) ion situated on an inversion center, one chloride anion, one tris­(4-meth­oxy­lphen­yl)phosphane (L) ligand and one acetone solvent mol­ecule. The Pt(II) ion is coordinated by two P atoms [Pt—P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt—Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P—Pt—Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C—H⋯O and C—H⋯Cl hydrogen bonds hold mol­ecules together.
format Online
Article
Text
id pubmed-3588736
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887362013-03-06 trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(2)(C(21)H(21)O(3)P)(2)]·2C(3)H(6)O, the asymmetric unit contains a Pt(II) ion situated on an inversion center, one chloride anion, one tris­(4-meth­oxy­lphen­yl)phosphane (L) ligand and one acetone solvent mol­ecule. The Pt(II) ion is coordinated by two P atoms [Pt—P = 2.3196 (5) Å] from two L ligands and two chloride anions [Pt—Cl = 2.3075 (5) Å] in a distorted square-planar geometry with P—Pt—Cl angles of 88.016 (16) and 91.984 (16)°. The effective cone angle of the phosphane ligand was calculated to be 156°. Weak C—H⋯O and C—H⋯Cl hydrogen bonds hold mol­ecules together. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588736/ /pubmed/23468701 http://dx.doi.org/10.1107/S1600536812045643 Text en © Alfred Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muller, Alfred
trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate
title trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate
title_full trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate
title_fullStr trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate
title_full_unstemmed trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate
title_short trans-Dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κP]platinum(II) acetone disolvate
title_sort trans-dichloridobis[tris­(4-meth­oxy­lphen­yl)phosphane-κp]platinum(ii) acetone disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588736/
https://www.ncbi.nlm.nih.gov/pubmed/23468701
http://dx.doi.org/10.1107/S1600536812045643
work_keys_str_mv AT mulleralfred transdichloridobistris4methoxylphenylphosphanekpplatinumiiacetonedisolvate

Ejemplares similares