cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate

In the title compound, [PdCl(2)(C(15)H(11)NO(3))(2)]·CHCl(3), the Pd(II) atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano­phenyl ligands. The mol­ecular conformation is stabilized by π–π stacking inter­action...

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Detalles Bibliográficos
Autores principales: Tskhovrebov, Alexander, Haukka, Matti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588737/
https://www.ncbi.nlm.nih.gov/pubmed/23468702
http://dx.doi.org/10.1107/S1600536812045801
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author Tskhovrebov, Alexander
Haukka, Matti
author_facet Tskhovrebov, Alexander
Haukka, Matti
author_sort Tskhovrebov, Alexander
collection PubMed
description In the title compound, [PdCl(2)(C(15)H(11)NO(3))(2)]·CHCl(3), the Pd(II) atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano­phenyl ligands. The mol­ecular conformation is stabilized by π–π stacking inter­actions [shortest centroid–centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C—H⋯O and C—H⋯Cl inter­actions involving the chloro­form solvent mol­ecules.
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spelling pubmed-35887372013-03-06 cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate Tskhovrebov, Alexander Haukka, Matti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(15)H(11)NO(3))(2)]·CHCl(3), the Pd(II) atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano­phenyl ligands. The mol­ecular conformation is stabilized by π–π stacking inter­actions [shortest centroid–centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C—H⋯O and C—H⋯Cl inter­actions involving the chloro­form solvent mol­ecules. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588737/ /pubmed/23468702 http://dx.doi.org/10.1107/S1600536812045801 Text en © Tskhovrebov and Haukka 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tskhovrebov, Alexander
Haukka, Matti
cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate
title cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate
title_full cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate
title_fullStr cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate
title_full_unstemmed cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate
title_short cis-Dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(II) chloro­form monosolvate
title_sort cis-dichloridobis(2-isocyano­phenyl 4-meth­oxy­benzoate)palladium(ii) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588737/
https://www.ncbi.nlm.nih.gov/pubmed/23468702
http://dx.doi.org/10.1107/S1600536812045801
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