Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate
The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C(8)H(18)N(3)O(2))(2)[Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)](C(9)H(16)N(3)O(4))(2)·2CH(3)CN, in...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588739/ https://www.ncbi.nlm.nih.gov/pubmed/23468704 http://dx.doi.org/10.1107/S160053681204620X |
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author | Buvailo, Andrii I. Pavlishchuk, Anna V. Penkova, Larysa V. Kotova, Natalia V. Haukka, Matti |
author_facet | Buvailo, Andrii I. Pavlishchuk, Anna V. Penkova, Larysa V. Kotova, Natalia V. Haukka, Matti |
author_sort | Buvailo, Andrii I. |
collection | PubMed |
description | The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C(8)H(18)N(3)O(2))(2)[Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)](C(9)H(16)N(3)O(4))(2)·2CH(3)CN, in which an inversion center is located at the midpoint of the Cu(2) unit in the center of the neutral [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] complex fragment. The Cu(2+) ions are connected by two N—O bridging groups [Cu⋯Cu separation = 4.0608 (5) Å] while the Cu(II) ions are five-coordinated in a square-pyramidal N(4)O coordination environment. The complex molecule co-crystallizes with two molecules of acetonitrile, two molecules of the protonated ligand (E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium and two negatively charged (E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate anions, which were probably formed as a result of condensation between (E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide and hydrogencarbonate anions. In the crystal, the complex fragment [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] and the ion pair C(8)H(18)N(3)O(2) (+.)C(9)H(16)N(3)O(4) (−) are connected via an extended system of hydrogen bonds. |
format | Online Article Text |
id | pubmed-3588739 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887392013-03-06 Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate Buvailo, Andrii I. Pavlishchuk, Anna V. Penkova, Larysa V. Kotova, Natalia V. Haukka, Matti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C(8)H(18)N(3)O(2))(2)[Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)](C(9)H(16)N(3)O(4))(2)·2CH(3)CN, in which an inversion center is located at the midpoint of the Cu(2) unit in the center of the neutral [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] complex fragment. The Cu(2+) ions are connected by two N—O bridging groups [Cu⋯Cu separation = 4.0608 (5) Å] while the Cu(II) ions are five-coordinated in a square-pyramidal N(4)O coordination environment. The complex molecule co-crystallizes with two molecules of acetonitrile, two molecules of the protonated ligand (E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium and two negatively charged (E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate anions, which were probably formed as a result of condensation between (E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide and hydrogencarbonate anions. In the crystal, the complex fragment [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] and the ion pair C(8)H(18)N(3)O(2) (+.)C(9)H(16)N(3)O(4) (−) are connected via an extended system of hydrogen bonds. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588739/ /pubmed/23468704 http://dx.doi.org/10.1107/S160053681204620X Text en © Buvailo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Buvailo, Andrii I. Pavlishchuk, Anna V. Penkova, Larysa V. Kotova, Natalia V. Haukka, Matti Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
title | Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
title_full | Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
title_fullStr | Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
title_full_unstemmed | Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
title_short | Bis{(E)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(E)-N-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(II)} bis((E)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
title_sort | bis{(e)-3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(e)-n-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamido(2−)]bis{[(e)-n-(3-amino-2,2-dimethylpropyl)-2-(hydroxyimino)propanamide]copper(ii)} bis((e)-{3-[2-(hydroxyimino)propanamido]-2,2-dimethylpropyl}carbamate) acetonitrile disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588739/ https://www.ncbi.nlm.nih.gov/pubmed/23468704 http://dx.doi.org/10.1107/S160053681204620X |
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