Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate

The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C(8)H(18)N(3)O(2))(2)[Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)](C(9)H(16)N(3)O(4))(2)·2CH(3)CN, in...

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Autores principales: Buvailo, Andrii I., Pavlishchuk, Anna V., Penkova, Larysa V., Kotova, Natalia V., Haukka, Matti
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
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Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588739/
https://www.ncbi.nlm.nih.gov/pubmed/23468704
http://dx.doi.org/10.1107/S160053681204620X
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author Buvailo, Andrii I.
Pavlishchuk, Anna V.
Penkova, Larysa V.
Kotova, Natalia V.
Haukka, Matti
author_facet Buvailo, Andrii I.
Pavlishchuk, Anna V.
Penkova, Larysa V.
Kotova, Natalia V.
Haukka, Matti
author_sort Buvailo, Andrii I.
collection PubMed
description The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C(8)H(18)N(3)O(2))(2)[Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)](C(9)H(16)N(3)O(4))(2)·2CH(3)CN, in which an inversion center is located at the midpoint of the Cu(2) unit in the center of the neutral [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] complex fragment. The Cu(2+) ions are connected by two N—O bridging groups [Cu⋯Cu separation = 4.0608 (5) Å] while the Cu(II) ions are five-coordinated in a square-pyramidal N(4)O coordination environment. The complex mol­ecule co-crystallizes with two mol­ecules of acetonitrile, two mol­ecules of the protonated ligand (E)-3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­propan-1-aminium and two negatively charged (E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate anions, which were probably formed as a result of condensation between (E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide and hydro­gencarbonate anions. In the crystal, the complex fragment [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] and the ion pair C(8)H(18)N(3)O(2) (+.)C(9)H(16)N(3)O(4) (−) are connected via an extended system of hydrogen bonds.
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spelling pubmed-35887392013-03-06 Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate Buvailo, Andrii I. Pavlishchuk, Anna V. Penkova, Larysa V. Kotova, Natalia V. Haukka, Matti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction between copper(II) nitrate and (E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide led to the formation of the dinuclear centrosymmetric copper(II) title complex, (C(8)H(18)N(3)O(2))(2)[Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)](C(9)H(16)N(3)O(4))(2)·2CH(3)CN, in which an inversion center is located at the midpoint of the Cu(2) unit in the center of the neutral [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] complex fragment. The Cu(2+) ions are connected by two N—O bridging groups [Cu⋯Cu separation = 4.0608 (5) Å] while the Cu(II) ions are five-coordinated in a square-pyramidal N(4)O coordination environment. The complex mol­ecule co-crystallizes with two mol­ecules of acetonitrile, two mol­ecules of the protonated ligand (E)-3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­propan-1-aminium and two negatively charged (E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate anions, which were probably formed as a result of condensation between (E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide and hydro­gencarbonate anions. In the crystal, the complex fragment [Cu(2)(C(8)H(15)N(3)O(2))(2)(C(8)H(17)N(3)O(2))(2)] and the ion pair C(8)H(18)N(3)O(2) (+.)C(9)H(16)N(3)O(4) (−) are connected via an extended system of hydrogen bonds. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588739/ /pubmed/23468704 http://dx.doi.org/10.1107/S160053681204620X Text en © Buvailo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Buvailo, Andrii I.
Pavlishchuk, Anna V.
Penkova, Larysa V.
Kotova, Natalia V.
Haukka, Matti
Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
title Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
title_full Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
title_fullStr Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
title_full_unstemmed Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
title_short Bis­{(E)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(E)-N-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(II)} bis­((E)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
title_sort bis­{(e)-3-[2-(hy­droxy­imino)­propan­amido]-2,2-dimethyl­propan-1-aminium} bis[μ-(e)-n-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamido­(2−)]bis­{[(e)-n-(3-amino-2,2-dimethyl­prop­yl)-2-(hy­droxy­imino)­propanamide]­copper(ii)} bis­((e)-{3-[2-(hy­droxy­imino)­propanamido]-2,2-dimethyl­prop­yl}carbamate) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588739/
https://www.ncbi.nlm.nih.gov/pubmed/23468704
http://dx.doi.org/10.1107/S160053681204620X
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