Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)

The mol­ecular structure of the title compound, [Cu(C(11)H(16)N(3)O(3)S)(2)], shows the Cu(II) atom with a distorted square-planar coordination geometry from the N(2)O(2) donor set of the two chelating 2-{[bis­(dimethyl­amino)­methyl­idene]amino}­benzene­sulfonate ligands. The Cu(II) atom lies 0.065...

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Detalles Bibliográficos
Autores principales: Neuba, Adam, Flörke, Ulrich, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588740/
https://www.ncbi.nlm.nih.gov/pubmed/23468705
http://dx.doi.org/10.1107/S1600536812046387
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author Neuba, Adam
Flörke, Ulrich
Henkel, Gerald
author_facet Neuba, Adam
Flörke, Ulrich
Henkel, Gerald
author_sort Neuba, Adam
collection PubMed
description The mol­ecular structure of the title compound, [Cu(C(11)H(16)N(3)O(3)S)(2)], shows the Cu(II) atom with a distorted square-planar coordination geometry from the N(2)O(2) donor set of the two chelating 2-{[bis­(dimethyl­amino)­methyl­idene]amino}­benzene­sulfonate ligands. The Cu(II) atom lies 0.065 (1) Å above the N(2)O(2) plane and the Cu—O [2 × 1.945 (2) Å] and Cu—N bond lengths [1.968 (3) and 1.962 (3) Å] lie in expected ranges. The two aromatic ring planes make a dihedral angle of 85.48 (1)°.
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spelling pubmed-35887402013-03-06 Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II) Neuba, Adam Flörke, Ulrich Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the title compound, [Cu(C(11)H(16)N(3)O(3)S)(2)], shows the Cu(II) atom with a distorted square-planar coordination geometry from the N(2)O(2) donor set of the two chelating 2-{[bis­(dimethyl­amino)­methyl­idene]amino}­benzene­sulfonate ligands. The Cu(II) atom lies 0.065 (1) Å above the N(2)O(2) plane and the Cu—O [2 × 1.945 (2) Å] and Cu—N bond lengths [1.968 (3) and 1.962 (3) Å] lie in expected ranges. The two aromatic ring planes make a dihedral angle of 85.48 (1)°. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588740/ /pubmed/23468705 http://dx.doi.org/10.1107/S1600536812046387 Text en © Neuba et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Neuba, Adam
Flörke, Ulrich
Henkel, Gerald
Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)
title Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)
title_full Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)
title_fullStr Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)
title_full_unstemmed Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)
title_short Bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κN}benzene­sulfonato-κN)copper(II)
title_sort bis(2-{[bis­(dimethyl­amino)­methyl­idene]amino-κn}benzene­sulfonato-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588740/
https://www.ncbi.nlm.nih.gov/pubmed/23468705
http://dx.doi.org/10.1107/S1600536812046387
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AT florkeulrich bis2bisdimethylaminomethylideneaminoknbenzenesulfonatokncopperii
AT henkelgerald bis2bisdimethylaminomethylideneaminoknbenzenesulfonatokncopperii

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