Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)

In the title compound, [Ni(C(9)H(12)O(2)PS(2))(2)], the Ni(II) atom resides on an inversion center and is coordinated by four S atoms [Ni—S = 2.2328 (4) and 2.2455 (3) Å] in a distorted square-planar geometry [S—Ni—S = 88.443 (13) and 91.557 (13)°]. In the crystal, mol­ecules related by translation...

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Detalles Bibliográficos
Autores principales: Sewpersad, Shirveen, Omondi, Bernard, Van Zyl, Werner E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588741/
https://www.ncbi.nlm.nih.gov/pubmed/23468706
http://dx.doi.org/10.1107/S1600536812046314
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author Sewpersad, Shirveen
Omondi, Bernard
Van Zyl, Werner E.
author_facet Sewpersad, Shirveen
Omondi, Bernard
Van Zyl, Werner E.
author_sort Sewpersad, Shirveen
collection PubMed
description In the title compound, [Ni(C(9)H(12)O(2)PS(2))(2)], the Ni(II) atom resides on an inversion center and is coordinated by four S atoms [Ni—S = 2.2328 (4) and 2.2455 (3) Å] in a distorted square-planar geometry [S—Ni—S = 88.443 (13) and 91.557 (13)°]. In the crystal, mol­ecules related by translation in [110] are linked into chains via weak C—H⋯O inter­actions. The crystal packing exhibits short inter­molecular S⋯S contacts of 3.3366 (5) Å.
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spelling pubmed-35887412013-03-06 Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II) Sewpersad, Shirveen Omondi, Bernard Van Zyl, Werner E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(12)O(2)PS(2))(2)], the Ni(II) atom resides on an inversion center and is coordinated by four S atoms [Ni—S = 2.2328 (4) and 2.2455 (3) Å] in a distorted square-planar geometry [S—Ni—S = 88.443 (13) and 91.557 (13)°]. In the crystal, mol­ecules related by translation in [110] are linked into chains via weak C—H⋯O inter­actions. The crystal packing exhibits short inter­molecular S⋯S contacts of 3.3366 (5) Å. International Union of Crystallography 2012-11-14 /pmc/articles/PMC3588741/ /pubmed/23468706 http://dx.doi.org/10.1107/S1600536812046314 Text en © Sewpersad et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sewpersad, Shirveen
Omondi, Bernard
Van Zyl, Werner E.
Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)
title Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)
title_full Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)
title_fullStr Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)
title_full_unstemmed Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)
title_short Bis[O-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S,S′]nickel(II)
title_sort bis[o-methyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) s,s′]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588741/
https://www.ncbi.nlm.nih.gov/pubmed/23468706
http://dx.doi.org/10.1107/S1600536812046314
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