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Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}

The title compound, [Hg(2)(C(11)H(16)O(2)PS(2))(4)], is a dinuclear complex with a distorted tetra­hedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg—...

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Detalles Bibliográficos
Autores principales: Sewpersad, Shirveen, Van Zyl, Werner E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588744/
https://www.ncbi.nlm.nih.gov/pubmed/23468709
http://dx.doi.org/10.1107/S1600536812046624
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author Sewpersad, Shirveen
Van Zyl, Werner E.
author_facet Sewpersad, Shirveen
Van Zyl, Werner E.
author_sort Sewpersad, Shirveen
collection PubMed
description The title compound, [Hg(2)(C(11)H(16)O(2)PS(2))(4)], is a dinuclear complex with a distorted tetra­hedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg—S bonds form two distinct pairs of long and short bonds. One pair includes both chelating and bridging Hg—S bonds with approximately equal bond lengths of 2.4042 (8) and 2.3997 (7) Å, respectively. The other pair is significantly longer at 2.9361 (9) and 2.8105 (8) Å, respectively. This pattern forms a center of inversion through the mol­ecule with an equal and opposite effect occurring at the other Hg(II) atom. The S—Hg—S angles vary widely from 76.26 (2) to 154.65 (3)°, indicative of a distorted tetra­hedral arrangement of the S atoms around the Hg(II) atom. The P—S bond lengths are 1.9681 (10) and 2.0519 (11)°, clearly indicating partial double-bond character in the former. The mol­ecule contains an inversion center situated between the two Hg(II) atoms.
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spelling pubmed-35887442013-03-06 Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)} Sewpersad, Shirveen Van Zyl, Werner E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Hg(2)(C(11)H(16)O(2)PS(2))(4)], is a dinuclear complex with a distorted tetra­hedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg—S bonds form two distinct pairs of long and short bonds. One pair includes both chelating and bridging Hg—S bonds with approximately equal bond lengths of 2.4042 (8) and 2.3997 (7) Å, respectively. The other pair is significantly longer at 2.9361 (9) and 2.8105 (8) Å, respectively. This pattern forms a center of inversion through the mol­ecule with an equal and opposite effect occurring at the other Hg(II) atom. The S—Hg—S angles vary widely from 76.26 (2) to 154.65 (3)°, indicative of a distorted tetra­hedral arrangement of the S atoms around the Hg(II) atom. The P—S bond lengths are 1.9681 (10) and 2.0519 (11)°, clearly indicating partial double-bond character in the former. The mol­ecule contains an inversion center situated between the two Hg(II) atoms. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588744/ /pubmed/23468709 http://dx.doi.org/10.1107/S1600536812046624 Text en © Sewpersad and Van Zyl 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sewpersad, Shirveen
Van Zyl, Werner E.
Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}
title Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}
title_full Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}
title_fullStr Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}
title_full_unstemmed Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}
title_short Bis[μ-O-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) S:S′]bis­{[O-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) S,S′]mercury(II)}
title_sort bis[μ-o-isopropyl (4-eth­oxy­phen­yl)dithio­phospho­nato-κ(2) s:s′]bis­{[o-iso­propyl (4-eth­oxy­phen­yl)dithio­phos­phonato-κ(2) s,s′]mercury(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588744/
https://www.ncbi.nlm.nih.gov/pubmed/23468709
http://dx.doi.org/10.1107/S1600536812046624
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