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Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2) S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2) S,S′]mercury(II)}
The title compound, [Hg(2)(C(11)H(16)O(2)PS(2))(4)], is a dinuclear complex with a distorted tetrahedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg—...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588744/ https://www.ncbi.nlm.nih.gov/pubmed/23468709 http://dx.doi.org/10.1107/S1600536812046624 |
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author | Sewpersad, Shirveen Van Zyl, Werner E. |
author_facet | Sewpersad, Shirveen Van Zyl, Werner E. |
author_sort | Sewpersad, Shirveen |
collection | PubMed |
description | The title compound, [Hg(2)(C(11)H(16)O(2)PS(2))(4)], is a dinuclear complex with a distorted tetrahedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg—S bonds form two distinct pairs of long and short bonds. One pair includes both chelating and bridging Hg—S bonds with approximately equal bond lengths of 2.4042 (8) and 2.3997 (7) Å, respectively. The other pair is significantly longer at 2.9361 (9) and 2.8105 (8) Å, respectively. This pattern forms a center of inversion through the molecule with an equal and opposite effect occurring at the other Hg(II) atom. The S—Hg—S angles vary widely from 76.26 (2) to 154.65 (3)°, indicative of a distorted tetrahedral arrangement of the S atoms around the Hg(II) atom. The P—S bond lengths are 1.9681 (10) and 2.0519 (11)°, clearly indicating partial double-bond character in the former. The molecule contains an inversion center situated between the two Hg(II) atoms. |
format | Online Article Text |
id | pubmed-3588744 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887442013-03-06 Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2) S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2) S,S′]mercury(II)} Sewpersad, Shirveen Van Zyl, Werner E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Hg(2)(C(11)H(16)O(2)PS(2))(4)], is a dinuclear complex with a distorted tetrahedral geometry around each Hg(II) atom. Although the two Hg(II) atoms are surrounded by the same ligand, two different coordination modes are observed: one is chelating and the other bridging. The Hg—S bonds form two distinct pairs of long and short bonds. One pair includes both chelating and bridging Hg—S bonds with approximately equal bond lengths of 2.4042 (8) and 2.3997 (7) Å, respectively. The other pair is significantly longer at 2.9361 (9) and 2.8105 (8) Å, respectively. This pattern forms a center of inversion through the molecule with an equal and opposite effect occurring at the other Hg(II) atom. The S—Hg—S angles vary widely from 76.26 (2) to 154.65 (3)°, indicative of a distorted tetrahedral arrangement of the S atoms around the Hg(II) atom. The P—S bond lengths are 1.9681 (10) and 2.0519 (11)°, clearly indicating partial double-bond character in the former. The molecule contains an inversion center situated between the two Hg(II) atoms. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588744/ /pubmed/23468709 http://dx.doi.org/10.1107/S1600536812046624 Text en © Sewpersad and Van Zyl 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sewpersad, Shirveen Van Zyl, Werner E. Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2) S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2) S,S′]mercury(II)} |
title | Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S,S′]mercury(II)} |
title_full | Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S,S′]mercury(II)} |
title_fullStr | Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S,S′]mercury(II)} |
title_full_unstemmed | Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S,S′]mercury(II)} |
title_short | Bis[μ-O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S:S′]bis{[O-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
S,S′]mercury(II)} |
title_sort | bis[μ-o-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
s:s′]bis{[o-isopropyl (4-ethoxyphenyl)dithiophosphonato-κ(2)
s,s′]mercury(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588744/ https://www.ncbi.nlm.nih.gov/pubmed/23468709 http://dx.doi.org/10.1107/S1600536812046624 |
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