rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate

The title compound, [Fe(C(5)H(5))(C(21)H(24)NPS)]I·CHCl(3), is built up from a (ferrocenylmeth­yl)trimethyl­ammonium cation, a iodine anion and a chloro­form solvent mol­ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the subst...

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Detalles Bibliográficos
Autores principales: Karpous, Andrei, Voitenko, Zoia, Daran, Jean-Claude, Manoury, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588745/
https://www.ncbi.nlm.nih.gov/pubmed/23468710
http://dx.doi.org/10.1107/S1600536812046053
Descripción
Sumario:The title compound, [Fe(C(5)H(5))(C(21)H(24)NPS)]I·CHCl(3), is built up from a (ferrocenylmeth­yl)trimethyl­ammonium cation, a iodine anion and a chloro­form solvent mol­ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the substituted cyclo­penta­dienyl (Cp) ring towards the Fe atom, whereas the C atom attached to the same Cp ring is slightly below this plane by −0.128 (2) Å. These deviations might result from weak agostic interactions between the two H atoms of the CH(2) group and the Fe atom.

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