rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate

The title compound, [Fe(C(5)H(5))(C(21)H(24)NPS)]I·CHCl(3), is built up from a (ferrocenylmeth­yl)trimethyl­ammonium cation, a iodine anion and a chloro­form solvent mol­ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the subst...

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Autores principales: Karpous, Andrei, Voitenko, Zoia, Daran, Jean-Claude, Manoury, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588745/
https://www.ncbi.nlm.nih.gov/pubmed/23468710
http://dx.doi.org/10.1107/S1600536812046053
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author Karpous, Andrei
Voitenko, Zoia
Daran, Jean-Claude
Manoury, Eric
author_facet Karpous, Andrei
Voitenko, Zoia
Daran, Jean-Claude
Manoury, Eric
author_sort Karpous, Andrei
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(21)H(24)NPS)]I·CHCl(3), is built up from a (ferrocenylmeth­yl)trimethyl­ammonium cation, a iodine anion and a chloro­form solvent mol­ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the substituted cyclo­penta­dienyl (Cp) ring towards the Fe atom, whereas the C atom attached to the same Cp ring is slightly below this plane by −0.128 (2) Å. These deviations might result from weak agostic interactions between the two H atoms of the CH(2) group and the Fe atom.
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spelling pubmed-35887452013-03-06 rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate Karpous, Andrei Voitenko, Zoia Daran, Jean-Claude Manoury, Eric Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(21)H(24)NPS)]I·CHCl(3), is built up from a (ferrocenylmeth­yl)trimethyl­ammonium cation, a iodine anion and a chloro­form solvent mol­ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the substituted cyclo­penta­dienyl (Cp) ring towards the Fe atom, whereas the C atom attached to the same Cp ring is slightly below this plane by −0.128 (2) Å. These deviations might result from weak agostic interactions between the two H atoms of the CH(2) group and the Fe atom. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588745/ /pubmed/23468710 http://dx.doi.org/10.1107/S1600536812046053 Text en © Karpous et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Karpous, Andrei
Voitenko, Zoia
Daran, Jean-Claude
Manoury, Eric
rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
title rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
title_full rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
title_fullStr rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
title_full_unstemmed rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
title_short rac-{[2-(Diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
title_sort rac-{[2-(diphenyl­thio­phosphan­yl)ferrocen­yl]meth­yl}trimethyl­ammonium iodide chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588745/
https://www.ncbi.nlm.nih.gov/pubmed/23468710
http://dx.doi.org/10.1107/S1600536812046053
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AT daranjeanclaude rac2diphenylthiophosphanylferrocenylmethyltrimethylammoniumiodidechloroformmonosolvate
AT manouryeric rac2diphenylthiophosphanylferrocenylmethyltrimethylammoniumiodidechloroformmonosolvate

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