catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]

In the crystal of the title polymeric compound, [CdBr(2)(C(12)H(12)N(2))](n), the Cd(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted octa­hedral geometry formed by two N atoms from the 4,4′-dimethyl-2,2′-bipyridine ligand and by four bridging Br(−) anions. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Khazali, Fereydoon, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588747/
https://www.ncbi.nlm.nih.gov/pubmed/23468712
http://dx.doi.org/10.1107/S1600536812046636
_version_ 1782261627662368768
author Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
author_sort Shirvan, Sadif A.
collection PubMed
description In the crystal of the title polymeric compound, [CdBr(2)(C(12)H(12)N(2))](n), the Cd(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted octa­hedral geometry formed by two N atoms from the 4,4′-dimethyl-2,2′-bipyridine ligand and by four bridging Br(−) anions. The bridging function of the Br(−) anions leads to a polymeric chain running along the c axis. Weak C—H⋯π inter­actions observed between adjacent chains are effective in the stabilization of the three-dimensional packing.
format Online
Article
Text
id pubmed-3588747
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887472013-03-06 catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido] Shirvan, Sadif A. Haydari Dezfuli, Sara Khazali, Fereydoon Borsalani, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title polymeric compound, [CdBr(2)(C(12)H(12)N(2))](n), the Cd(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted octa­hedral geometry formed by two N atoms from the 4,4′-dimethyl-2,2′-bipyridine ligand and by four bridging Br(−) anions. The bridging function of the Br(−) anions leads to a polymeric chain running along the c axis. Weak C—H⋯π inter­actions observed between adjacent chains are effective in the stabilization of the three-dimensional packing. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588747/ /pubmed/23468712 http://dx.doi.org/10.1107/S1600536812046636 Text en © Shirvan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]
title catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]
title_full catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]
title_fullStr catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]
title_full_unstemmed catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]
title_short catena-Poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium]-di-μ-bromido]
title_sort catena-poly[[(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)cadmium]-di-μ-bromido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588747/
https://www.ncbi.nlm.nih.gov/pubmed/23468712
http://dx.doi.org/10.1107/S1600536812046636
work_keys_str_mv AT shirvansadifa catenapoly44dimethyl22bipyridinek2nncadmiumdimbromido
AT haydaridezfulisara catenapoly44dimethyl22bipyridinek2nncadmiumdimbromido
AT khazalifereydoon catenapoly44dimethyl22bipyridinek2nncadmiumdimbromido
AT borsalaniali catenapoly44dimethyl22bipyridinek2nncadmiumdimbromido

Ejemplares similares