Bis[2-({[2-(methyl­sulfan­yl)phen­yl]imino}­meth­yl)phenolato-κ(2) N,O]zinc chloro­form disolvate

The monomeric title complex, [Zn(C(14)H(12)NOS)(2)]·2CHCl(3) or L (2)Zn·2CHCl(3), where L is the 2-({[2-(methyl­sulfan­yl)phen­yl]imino}­meth­yl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt(2) in tetra­hydro­furan...

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Detalles Bibliográficos
Autores principales: Chen, Yen-Jen, Hsiao, Mon-Wei, Jheng, Nai-Yuan, Lai, Yi-Chun, Chen, Hsuan-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588749/
https://www.ncbi.nlm.nih.gov/pubmed/23468714
http://dx.doi.org/10.1107/S1600536812045473
Descripción
Sumario:The monomeric title complex, [Zn(C(14)H(12)NOS)(2)]·2CHCl(3) or L (2)Zn·2CHCl(3), where L is the 2-({[2-(methyl­sulfan­yl)phen­yl]imino}­meth­yl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt(2) in tetra­hydro­furan. The Zn atom, located on a twofold axis, is four-coordinated in a distorted tetra­hedral geometry by two O atoms [Zn—O = 1.9472 (19) Å] from the phenolate anions and two imine N atoms [Zn—N = 2.054 (2) Å].

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