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Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2) N,O]zinc chloroform disolvate
The monomeric title complex, [Zn(C(14)H(12)NOS)(2)]·2CHCl(3) or L (2)Zn·2CHCl(3), where L is the 2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt(2) in tetrahydrofuran...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588749/ https://www.ncbi.nlm.nih.gov/pubmed/23468714 http://dx.doi.org/10.1107/S1600536812045473 |
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| author | Chen, Yen-Jen Hsiao, Mon-Wei Jheng, Nai-Yuan Lai, Yi-Chun Chen, Hsuan-Ying |
| author_facet | Chen, Yen-Jen Hsiao, Mon-Wei Jheng, Nai-Yuan Lai, Yi-Chun Chen, Hsuan-Ying |
| author_sort | Chen, Yen-Jen |
| collection | PubMed |
| description | The monomeric title complex, [Zn(C(14)H(12)NOS)(2)]·2CHCl(3) or L (2)Zn·2CHCl(3), where L is the 2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt(2) in tetrahydrofuran. The Zn atom, located on a twofold axis, is four-coordinated in a distorted tetrahedral geometry by two O atoms [Zn—O = 1.9472 (19) Å] from the phenolate anions and two imine N atoms [Zn—N = 2.054 (2) Å]. |
| format | Online Article Text |
| id | pubmed-3588749 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887492013-03-06 Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2) N,O]zinc chloroform disolvate Chen, Yen-Jen Hsiao, Mon-Wei Jheng, Nai-Yuan Lai, Yi-Chun Chen, Hsuan-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The monomeric title complex, [Zn(C(14)H(12)NOS)(2)]·2CHCl(3) or L (2)Zn·2CHCl(3), where L is the 2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt(2) in tetrahydrofuran. The Zn atom, located on a twofold axis, is four-coordinated in a distorted tetrahedral geometry by two O atoms [Zn—O = 1.9472 (19) Å] from the phenolate anions and two imine N atoms [Zn—N = 2.054 (2) Å]. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588749/ /pubmed/23468714 http://dx.doi.org/10.1107/S1600536812045473 Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Yen-Jen Hsiao, Mon-Wei Jheng, Nai-Yuan Lai, Yi-Chun Chen, Hsuan-Ying Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2) N,O]zinc chloroform disolvate |
| title | Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2)
N,O]zinc chloroform disolvate |
| title_full | Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2)
N,O]zinc chloroform disolvate |
| title_fullStr | Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2)
N,O]zinc chloroform disolvate |
| title_full_unstemmed | Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2)
N,O]zinc chloroform disolvate |
| title_short | Bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2)
N,O]zinc chloroform disolvate |
| title_sort | bis[2-({[2-(methylsulfanyl)phenyl]imino}methyl)phenolato-κ(2)
n,o]zinc chloroform disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588749/ https://www.ncbi.nlm.nih.gov/pubmed/23468714 http://dx.doi.org/10.1107/S1600536812045473 |
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