Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate

In the mononuclear title salt, (C(5)H(6)N)(2)[Cu(C(5)H(2)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Cu(II) ion is located on an inversion centre and is coordinated by two chelating pyrazole-3,5-dicarboxyl­ate anions and two water mol­ecules, forming a Jahn–Teller-distorted CuN(2)O(4) octa­hedron. O—H⋯O and...

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Detalles Bibliográficos
Autor principal: Si, Youtao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588750/
https://www.ncbi.nlm.nih.gov/pubmed/23468715
http://dx.doi.org/10.1107/S1600536812046508
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author Si, Youtao
author_facet Si, Youtao
author_sort Si, Youtao
collection PubMed
description In the mononuclear title salt, (C(5)H(6)N)(2)[Cu(C(5)H(2)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Cu(II) ion is located on an inversion centre and is coordinated by two chelating pyrazole-3,5-dicarboxyl­ate anions and two water mol­ecules, forming a Jahn–Teller-distorted CuN(2)O(4) octa­hedron. O—H⋯O and N—H⋯O hydrogen bonds are formed between water mol­ecules, complex anions and the pyridine counter-cations, leading to the formation of layers parallel to (100). The layers are held together by weak C—H⋯O hydrogen bonds.
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spelling pubmed-35887502013-03-06 Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate Si, Youtao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title salt, (C(5)H(6)N)(2)[Cu(C(5)H(2)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Cu(II) ion is located on an inversion centre and is coordinated by two chelating pyrazole-3,5-dicarboxyl­ate anions and two water mol­ecules, forming a Jahn–Teller-distorted CuN(2)O(4) octa­hedron. O—H⋯O and N—H⋯O hydrogen bonds are formed between water mol­ecules, complex anions and the pyridine counter-cations, leading to the formation of layers parallel to (100). The layers are held together by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588750/ /pubmed/23468715 http://dx.doi.org/10.1107/S1600536812046508 Text en © Youtao Si 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Si, Youtao
Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate
title Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate
title_full Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate
title_fullStr Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate
title_full_unstemmed Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate
title_short Dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) N,O)cuprate(II) dihydrate
title_sort dipyridinium diaqua­bis­(pyrazole-3,5-di­carboxyl­ato-κ(2) n,o)cuprate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588750/
https://www.ncbi.nlm.nih.gov/pubmed/23468715
http://dx.doi.org/10.1107/S1600536812046508
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