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Bis(2,4-dimethylpyridinium) tetrabromidomercurate(II)
The asymmetric unit of the title compound, (C(7)H(10)N)(2)[HgBr(4)], consists of one cation and one half-anion, bisected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetrahedral arrangement about the Hg(II) atom. In the crystal, the cations and anions a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588751/ https://www.ncbi.nlm.nih.gov/pubmed/23468716 http://dx.doi.org/10.1107/S1600536812046788 |
Sumario: | The asymmetric unit of the title compound, (C(7)H(10)N)(2)[HgBr(4)], consists of one cation and one half-anion, bisected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetrahedral arrangement about the Hg(II) atom. In the crystal, the cations and anions are linked by N—H⋯Br hydrogen-bonding interactions along [010]. Cation–cation π–π stacking and Br⋯Br intermolecular interactions are absent. |
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