Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)

The asymmetric unit of the title compound, (C(7)H(10)N)(2)[HgBr(4)], consists of one cation and one half-anion, bis­ected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetra­hedral arrangement about the Hg(II) atom. In the crystal, the cations and anions a...

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Detalles Bibliográficos
Autores principales: Al-Far, Rawhi, Haddad, Salim F., Ali, Basem F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588751/
https://www.ncbi.nlm.nih.gov/pubmed/23468716
http://dx.doi.org/10.1107/S1600536812046788
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author Al-Far, Rawhi
Haddad, Salim F.
Ali, Basem F.
author_facet Al-Far, Rawhi
Haddad, Salim F.
Ali, Basem F.
author_sort Al-Far, Rawhi
collection PubMed
description The asymmetric unit of the title compound, (C(7)H(10)N)(2)[HgBr(4)], consists of one cation and one half-anion, bis­ected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetra­hedral arrangement about the Hg(II) atom. In the crystal, the cations and anions are linked by N—H⋯Br hydrogen-bonding inter­actions along [010]. Cation–cation π–π stacking and Br⋯Br inter­molecular inter­actions are absent.
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spelling pubmed-35887512013-03-06 Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II) Al-Far, Rawhi Haddad, Salim F. Ali, Basem F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(7)H(10)N)(2)[HgBr(4)], consists of one cation and one half-anion, bis­ected by a twofold rotation axis passing through the metal atom. The anion exhibits a distorted tetra­hedral arrangement about the Hg(II) atom. In the crystal, the cations and anions are linked by N—H⋯Br hydrogen-bonding inter­actions along [010]. Cation–cation π–π stacking and Br⋯Br inter­molecular inter­actions are absent. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588751/ /pubmed/23468716 http://dx.doi.org/10.1107/S1600536812046788 Text en © Al-Far et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Al-Far, Rawhi
Haddad, Salim F.
Ali, Basem F.
Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)
title Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)
title_full Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)
title_fullStr Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)
title_full_unstemmed Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)
title_short Bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(II)
title_sort bis(2,4-dimethyl­pyridinium) tetra­bromido­mercurate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588751/
https://www.ncbi.nlm.nih.gov/pubmed/23468716
http://dx.doi.org/10.1107/S1600536812046788
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AT haddadsalimf bis24dimethylpyridiniumtetrabromidomercurateii
AT alibasemf bis24dimethylpyridiniumtetrabromidomercurateii

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