A salen-type trinuclear Zn(2)Gd complex

In the trinuclear title complex, di-μ-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(methanylyl­idene)]diphenolato}-1:2κ(6) O (1),N,N′,O (1′):O (6),O (6′);2:3κ(6) O (6),O (6′):O (1),N,N′,O (1′)-2-gadolinium(III)-1,3-dizinc hexa­fluor­idophosphate methanol monosolvate monohydrate, [GdZn(2)(C(22)H(24)N(2)O(4))(2)(CH(3)COO)(2)]PF(6)·CH(3)OH·H(2)O, the two Zn(II) ions are located in the inner N(2)O(2) cavities of two 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(methanylyl­idene)]diphenolate (L) ligands. Both Zn(II) ions are five-coordinated by two O atoms and two N atoms from the L ligand and one O atom of an acetic acid mol­ecule, giving rise to a square-pyramidal geometry around the Zn(II) ions. The Gd(III) ion is nine-coordinated by four O atoms from the outer O(2)O(2) sites of one ligand, and three O atoms from another ligand, in which there is one non-coordinating meth­oxy O atom. Two further O atom from different acetate ligands complete the nine-coordinate environment.