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catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2) N (3):N (3′)]] naphthalene-1,5-disulfonate]
In the title complex, {[Cu(C(11)H(16)N(4))(2)(H(2)O)(2)](C(10)H(6)O(6)S(2))}(n), the Cu(II) atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent Cu(II...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588755/ https://www.ncbi.nlm.nih.gov/pubmed/23468720 http://dx.doi.org/10.1107/S1600536812045679 |
| _version_ | 1782261629485842432 |
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| author | Zhang, Lai-Ping Wen, Shu-Tang Fu, Xiao-Ning |
| author_facet | Zhang, Lai-Ping Wen, Shu-Tang Fu, Xiao-Ning |
| author_sort | Zhang, Lai-Ping |
| collection | PubMed |
| description | In the title complex, {[Cu(C(11)H(16)N(4))(2)(H(2)O)(2)](C(10)H(6)O(6)S(2))}(n), the Cu(II) atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent Cu(II) atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O—H⋯O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11). |
| format | Online Article Text |
| id | pubmed-3588755 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887552013-03-06 catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2) N (3):N (3′)]] naphthalene-1,5-disulfonate] Zhang, Lai-Ping Wen, Shu-Tang Fu, Xiao-Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(C(11)H(16)N(4))(2)(H(2)O)(2)](C(10)H(6)O(6)S(2))}(n), the Cu(II) atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent Cu(II) atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O—H⋯O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11). International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588755/ /pubmed/23468720 http://dx.doi.org/10.1107/S1600536812045679 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Lai-Ping Wen, Shu-Tang Fu, Xiao-Ning catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2) N (3):N (3′)]] naphthalene-1,5-disulfonate] |
| title |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2)
N
(3):N
(3′)]] naphthalene-1,5-disulfonate] |
| title_full |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2)
N
(3):N
(3′)]] naphthalene-1,5-disulfonate] |
| title_fullStr |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2)
N
(3):N
(3′)]] naphthalene-1,5-disulfonate] |
| title_full_unstemmed |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2)
N
(3):N
(3′)]] naphthalene-1,5-disulfonate] |
| title_short |
catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ(2)
N
(3):N
(3′)]] naphthalene-1,5-disulfonate] |
| title_sort | catena-poly[[[diaquacopper(ii)]-bis[μ-1,5-bis(1h-imidazol-1-yl)pentane-κ(2)
n
(3):n
(3′)]] naphthalene-1,5-disulfonate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588755/ https://www.ncbi.nlm.nih.gov/pubmed/23468720 http://dx.doi.org/10.1107/S1600536812045679 |
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