(1-Acetyl­thio­urea-κS)bromido­bis(triphenyl­phosphane-κP)silver(I)

In the title complex, [AgBr(C(3)H(6)N(2)OS)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral geometry coordinated by two P atoms from two triphenyl­phosphane ligands, one S atom of an acetyl­thio­urea ligand and one bromide ligand. There are intra­molecular N—H⋯Br and N—H⋯O hydrogen bo...

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Detalles Bibliográficos
Autores principales: Pakawatchai, Chaveng, Jantaramas, Piyapong, Mokhagul, Jedsada, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588756/
https://www.ncbi.nlm.nih.gov/pubmed/23468721
http://dx.doi.org/10.1107/S1600536812045199
Descripción
Sumario:In the title complex, [AgBr(C(3)H(6)N(2)OS)(C(18)H(15)P)(2)], the Ag(I) ion is in a distorted tetra­hedral geometry coordinated by two P atoms from two triphenyl­phosphane ligands, one S atom of an acetyl­thio­urea ligand and one bromide ligand. There are intra­molecular N—H⋯Br and N—H⋯O hydrogen bonds present. In the crystal, pairs of N—H⋯S hydrogen bonds involving thio­urea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an inter­molecular P⋯P distance of 6.4586 (17) Å.

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