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trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate
The title compound, [PdCl(2)(C(21)H(12)F(9)P)(2)]·CH(2)Cl(2), crystallizes with two independent complex molecules (each having the Pd(II) atom situated on an inversion centre) and a dichloromethane molecule in the asymmetric unit. The independent Pd(II) atoms are in perfectly linear orientations of...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588757/ https://www.ncbi.nlm.nih.gov/pubmed/23468722 http://dx.doi.org/10.1107/S1600536812046971 |
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author | Davis, Wade L. Muller, Alfred |
author_facet | Davis, Wade L. Muller, Alfred |
author_sort | Davis, Wade L. |
collection | PubMed |
description | The title compound, [PdCl(2)(C(21)H(12)F(9)P)(2)]·CH(2)Cl(2), crystallizes with two independent complex molecules (each having the Pd(II) atom situated on an inversion centre) and a dichloromethane molecule in the asymmetric unit. The independent Pd(II) atoms are in perfectly linear orientations of the ligands in mutually trans positions, but distortions of the Cl—Pd—P angles ranging from 86.151 (19) to 93.849 (19)° are evident. The effective cone angles for the tris[4-(trifluoromethyl)phenyl]phosphane ligand were calculated to be 159 and 161°. In the crystal, weak C—H⋯Cl/F interactions create a three-dimensional supramolecular network. Loose packing at two of the –CF(3) groups resulted in large thermal vibrations which were treated as two-component disorders [occupancy ratios 0.50:0.50 and 0.628 (15):0.372 (15)]. |
format | Online Article Text |
id | pubmed-3588757 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887572013-03-06 trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate Davis, Wade L. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(21)H(12)F(9)P)(2)]·CH(2)Cl(2), crystallizes with two independent complex molecules (each having the Pd(II) atom situated on an inversion centre) and a dichloromethane molecule in the asymmetric unit. The independent Pd(II) atoms are in perfectly linear orientations of the ligands in mutually trans positions, but distortions of the Cl—Pd—P angles ranging from 86.151 (19) to 93.849 (19)° are evident. The effective cone angles for the tris[4-(trifluoromethyl)phenyl]phosphane ligand were calculated to be 159 and 161°. In the crystal, weak C—H⋯Cl/F interactions create a three-dimensional supramolecular network. Loose packing at two of the –CF(3) groups resulted in large thermal vibrations which were treated as two-component disorders [occupancy ratios 0.50:0.50 and 0.628 (15):0.372 (15)]. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588757/ /pubmed/23468722 http://dx.doi.org/10.1107/S1600536812046971 Text en © Davis and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Davis, Wade L. Muller, Alfred trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate |
title |
trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate |
title_full |
trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate |
title_fullStr |
trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate |
title_full_unstemmed |
trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate |
title_short |
trans-Dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κP}palladium(II) dichloromethane monosolvate |
title_sort | trans-dichloridobis{tris[4-(trifluoromethyl)phenyl]phosphane-κp}palladium(ii) dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588757/ https://www.ncbi.nlm.nih.gov/pubmed/23468722 http://dx.doi.org/10.1107/S1600536812046971 |
work_keys_str_mv | AT daviswadel transdichloridobistris4trifluoromethylphenylphosphanekppalladiumiidichloromethanemonosolvate AT mulleralfred transdichloridobistris4trifluoromethylphenylphosphanekppalladiumiidichloromethanemonosolvate |