Cargando…

Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]

In the dinuclear centrosymmetric title compound, [Cd(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) ion is chelated by two carboxyl­ate groups from 4-methyl­benzoate anions, and is further coordinated by one nicotinamide and one water mol­ecule; a carboxyl­ate O atom from an adjacent 4...

Descripción completa

Detalles Bibliográficos
Autores principales: Dincel, Öznur, Tercan, Barış, Çimen, Efdal, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588758/
https://www.ncbi.nlm.nih.gov/pubmed/23468723
http://dx.doi.org/10.1107/S1600536812047046
_version_ 1782261630176854016
author Dincel, Öznur
Tercan, Barış
Çimen, Efdal
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Dincel, Öznur
Tercan, Barış
Çimen, Efdal
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Dincel, Öznur
collection PubMed
description In the dinuclear centrosymmetric title compound, [Cd(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) ion is chelated by two carboxyl­ate groups from 4-methyl­benzoate anions, and is further coordinated by one nicotinamide and one water mol­ecule; a carboxyl­ate O atom from an adjacent 4-methyl­benzoate anion bridges to the Cd(II) ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, inter­molecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. The methyl­benzene moiety of one bridging 4-methyl­benzoate anion is disordered over two orientations of equal occupancy.
format Online
Article
Text
id pubmed-3588758
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887582013-03-06 Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium] Dincel, Öznur Tercan, Barış Çimen, Efdal Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear centrosymmetric title compound, [Cd(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) ion is chelated by two carboxyl­ate groups from 4-methyl­benzoate anions, and is further coordinated by one nicotinamide and one water mol­ecule; a carboxyl­ate O atom from an adjacent 4-methyl­benzoate anion bridges to the Cd(II) ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, inter­molecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. The methyl­benzene moiety of one bridging 4-methyl­benzoate anion is disordered over two orientations of equal occupancy. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588758/ /pubmed/23468723 http://dx.doi.org/10.1107/S1600536812047046 Text en © Dincel et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dincel, Öznur
Tercan, Barış
Çimen, Efdal
Necefoğlu, Hacali
Hökelek, Tuncer
Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
title Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
title_full Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
title_fullStr Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
title_full_unstemmed Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
title_short Bis(μ-4-methyl­benzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis­[aqua­(4-methyl­benzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
title_sort bis(μ-4-methyl­benzoato)-κ(3) o,o′:o;κ(3) o:o,o′-bis­[aqua­(4-methyl­benzoato-κ(2) o,o′)(nicotinamide-κn (1))cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588758/
https://www.ncbi.nlm.nih.gov/pubmed/23468723
http://dx.doi.org/10.1107/S1600536812047046
work_keys_str_mv AT dinceloznur bism4methylbenzoatok3oook3ooobisaqua4methylbenzoatok2oonicotinamidekn1cadmium
AT tercanbarıs bism4methylbenzoatok3oook3ooobisaqua4methylbenzoatok2oonicotinamidekn1cadmium
AT cimenefdal bism4methylbenzoatok3oook3ooobisaqua4methylbenzoatok2oonicotinamidekn1cadmium
AT necefogluhacali bism4methylbenzoatok3oook3ooobisaqua4methylbenzoatok2oonicotinamidekn1cadmium
AT hokelektuncer bism4methylbenzoatok3oook3ooobisaqua4methylbenzoatok2oonicotinamidekn1cadmium