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Bis(μ-4-methylbenzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis[aqua(4-methylbenzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium]
In the dinuclear centrosymmetric title compound, [Cd(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588758/ https://www.ncbi.nlm.nih.gov/pubmed/23468723 http://dx.doi.org/10.1107/S1600536812047046 |
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author | Dincel, Öznur Tercan, Barış Çimen, Efdal Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Dincel, Öznur Tercan, Barış Çimen, Efdal Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Dincel, Öznur |
collection | PubMed |
description | In the dinuclear centrosymmetric title compound, [Cd(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the Cd(II) ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy. |
format | Online Article Text |
id | pubmed-3588758 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887582013-03-06 Bis(μ-4-methylbenzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis[aqua(4-methylbenzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium] Dincel, Öznur Tercan, Barış Çimen, Efdal Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear centrosymmetric title compound, [Cd(2)(C(8)H(7)O(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the Cd(II) ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588758/ /pubmed/23468723 http://dx.doi.org/10.1107/S1600536812047046 Text en © Dincel et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dincel, Öznur Tercan, Barış Çimen, Efdal Necefoğlu, Hacali Hökelek, Tuncer Bis(μ-4-methylbenzoato)-κ(3) O,O′:O;κ(3) O:O,O′-bis[aqua(4-methylbenzoato-κ(2) O,O′)(nicotinamide-κN (1))cadmium] |
title | Bis(μ-4-methylbenzoato)-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[aqua(4-methylbenzoato-κ(2)
O,O′)(nicotinamide-κN
(1))cadmium] |
title_full | Bis(μ-4-methylbenzoato)-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[aqua(4-methylbenzoato-κ(2)
O,O′)(nicotinamide-κN
(1))cadmium] |
title_fullStr | Bis(μ-4-methylbenzoato)-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[aqua(4-methylbenzoato-κ(2)
O,O′)(nicotinamide-κN
(1))cadmium] |
title_full_unstemmed | Bis(μ-4-methylbenzoato)-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[aqua(4-methylbenzoato-κ(2)
O,O′)(nicotinamide-κN
(1))cadmium] |
title_short | Bis(μ-4-methylbenzoato)-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[aqua(4-methylbenzoato-κ(2)
O,O′)(nicotinamide-κN
(1))cadmium] |
title_sort | bis(μ-4-methylbenzoato)-κ(3)
o,o′:o;κ(3)
o:o,o′-bis[aqua(4-methylbenzoato-κ(2)
o,o′)(nicotinamide-κn
(1))cadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588758/ https://www.ncbi.nlm.nih.gov/pubmed/23468723 http://dx.doi.org/10.1107/S1600536812047046 |
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