trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)

In the mononuclear title compound, trans-[PtCl(2)(C(19)H(17)P)(2)], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl­diphenyl­phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane li...

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Detalles Bibliográficos
Autor principal: Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588759/
https://www.ncbi.nlm.nih.gov/pubmed/23468724
http://dx.doi.org/10.1107/S160053681204696X
Descripción
Sumario:In the mononuclear title compound, trans-[PtCl(2)(C(19)H(17)P)(2)], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl­diphenyl­phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C—H⋯Cl inter­actions generate infinite long chains along [01-1]. Additional C—H⋯π and π–π stacking interactions [centroid–centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.

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