trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)

In the mononuclear title compound, trans-[PtCl(2)(C(19)H(17)P)(2)], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl­diphenyl­phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane li...

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Detalles Bibliográficos
Autor principal: Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588759/
https://www.ncbi.nlm.nih.gov/pubmed/23468724
http://dx.doi.org/10.1107/S160053681204696X
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author Muller, Alfred
author_facet Muller, Alfred
author_sort Muller, Alfred
collection PubMed
description In the mononuclear title compound, trans-[PtCl(2)(C(19)H(17)P)(2)], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl­diphenyl­phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C—H⋯Cl inter­actions generate infinite long chains along [01-1]. Additional C—H⋯π and π–π stacking interactions [centroid–centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.
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spelling pubmed-35887592013-03-06 trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, trans-[PtCl(2)(C(19)H(17)P)(2)], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl­diphenyl­phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C—H⋯Cl inter­actions generate infinite long chains along [01-1]. Additional C—H⋯π and π–π stacking interactions [centroid–centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588759/ /pubmed/23468724 http://dx.doi.org/10.1107/S160053681204696X Text en © Alfred Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muller, Alfred
trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)
title trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)
title_full trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)
title_fullStr trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)
title_full_unstemmed trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)
title_short trans-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II)
title_sort trans-bis(benzyl­diphenyl­phosphane-κp)dichloridoplatinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588759/
https://www.ncbi.nlm.nih.gov/pubmed/23468724
http://dx.doi.org/10.1107/S160053681204696X
work_keys_str_mv AT mulleralfred transbisbenzyldiphenylphosphanekpdichloridoplatinumii

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