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cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3) P,C (1),P′}chloridopalladium(II)
The Pd(II) atom in the title compound, [Pd(C(24)H(49)P(2))Cl], has a distorted square-planar CClP(2) coordination geometry with the P,C,P′-tridentate ligand forming two five-membered metallacycles. The cyclohexane ring is aligned with the Pd(II) coordination plane due to C—H activation in an equato...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588760/ https://www.ncbi.nlm.nih.gov/pubmed/23468725 http://dx.doi.org/10.1107/S1600536812047022 |
| _version_ | 1782261630623547392 |
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| author | Olsson, Daniel Janse van Rensburg, J. Marthinus Wendt, Ola F. |
| author_facet | Olsson, Daniel Janse van Rensburg, J. Marthinus Wendt, Ola F. |
| author_sort | Olsson, Daniel |
| collection | PubMed |
| description | The Pd(II) atom in the title compound, [Pd(C(24)H(49)P(2))Cl], has a distorted square-planar CClP(2) coordination geometry with the P,C,P′-tridentate ligand forming two five-membered metallacycles. The cyclohexane ring is aligned with the Pd(II) coordination plane due to C—H activation in an equatorial position, giving a tri-equatorial conformation of the cyclohexyl ring. |
| format | Online Article Text |
| id | pubmed-3588760 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887602013-03-06 cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3) P,C (1),P′}chloridopalladium(II) Olsson, Daniel Janse van Rensburg, J. Marthinus Wendt, Ola F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) atom in the title compound, [Pd(C(24)H(49)P(2))Cl], has a distorted square-planar CClP(2) coordination geometry with the P,C,P′-tridentate ligand forming two five-membered metallacycles. The cyclohexane ring is aligned with the Pd(II) coordination plane due to C—H activation in an equatorial position, giving a tri-equatorial conformation of the cyclohexyl ring. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588760/ /pubmed/23468725 http://dx.doi.org/10.1107/S1600536812047022 Text en © Olsson et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Olsson, Daniel Janse van Rensburg, J. Marthinus Wendt, Ola F. cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3) P,C (1),P′}chloridopalladium(II) |
| title |
cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3)
P,C
(1),P′}chloridopalladium(II) |
| title_full |
cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3)
P,C
(1),P′}chloridopalladium(II) |
| title_fullStr |
cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3)
P,C
(1),P′}chloridopalladium(II) |
| title_full_unstemmed |
cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3)
P,C
(1),P′}chloridopalladium(II) |
| title_short |
cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3)
P,C
(1),P′}chloridopalladium(II) |
| title_sort | cis-{2,6-bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3)
p,c
(1),p′}chloridopalladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588760/ https://www.ncbi.nlm.nih.gov/pubmed/23468725 http://dx.doi.org/10.1107/S1600536812047022 |
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