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cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-κ(3) P,C (1),P′}chloridopalladium(II)
The Pd(II) atom in the title compound, [Pd(C(24)H(49)P(2))Cl], has a distorted square-planar CClP(2) coordination geometry with the P,C,P′-tridentate ligand forming two five-membered metallacycles. The cyclohexane ring is aligned with the Pd(II) coordination plane due to C—H activation in an equato...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588760/ https://www.ncbi.nlm.nih.gov/pubmed/23468725 http://dx.doi.org/10.1107/S1600536812047022 |