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cis-{2,6-Bis[(di-tert-butyl­phosphan­yl)meth­yl]cyclo­hexyl-κ(3) P,C (1),P′}chloridopalladium(II)

The Pd(II) atom in the title compound, [Pd(C(24)H(49)P(2))Cl], has a distorted square-planar CClP(2) coordination geometry with the P,C,P′-tridentate ligand forming two five-membered metallacycles. The cyclo­hexane ring is aligned with the Pd(II) coordination plane due to C—H activation in an equato...

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Detalles Bibliográficos
Autores principales: Olsson, Daniel, Janse van Rensburg, J. Marthinus, Wendt, Ola F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588760/
https://www.ncbi.nlm.nih.gov/pubmed/23468725
http://dx.doi.org/10.1107/S1600536812047022