(1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium

The Cd(II) atom in the title complex, [Cd(C(12)H(27)O(3)SSi)(2)(C(3)H(4)N(2))], is penta-coordinated by two O and two S atoms from the O,S-chelating silane­thiol­ate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal–bipyramidal than to square-based pyramidal...

Descripción completa

Detalles Bibliográficos
Autores principales: Baranowska, Katarzyna, Bulman, Mateusz, Dołęga, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588762/
https://www.ncbi.nlm.nih.gov/pubmed/23468727
http://dx.doi.org/10.1107/S1600536812047186
_version_ 1782261631073386496
author Baranowska, Katarzyna
Bulman, Mateusz
Dołęga, Anna
author_facet Baranowska, Katarzyna
Bulman, Mateusz
Dołęga, Anna
author_sort Baranowska, Katarzyna
collection PubMed
description The Cd(II) atom in the title complex, [Cd(C(12)H(27)O(3)SSi)(2)(C(3)H(4)N(2))], is penta-coordinated by two O and two S atoms from the O,S-chelating silane­thiol­ate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal–bipyramidal than to square-based pyramidal. The pyrazole ligand is stabilized within the complex by an intra­molecular N—H⋯O hydrogen bond. One of the tert-butyl groups is disordered over two orientations with occupancy ratio of 0.534 (6):0.466 (6).
format Online
Article
Text
id pubmed-3588762
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887622013-03-06 (1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium Baranowska, Katarzyna Bulman, Mateusz Dołęga, Anna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title complex, [Cd(C(12)H(27)O(3)SSi)(2)(C(3)H(4)N(2))], is penta-coordinated by two O and two S atoms from the O,S-chelating silane­thiol­ate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal–bipyramidal than to square-based pyramidal. The pyrazole ligand is stabilized within the complex by an intra­molecular N—H⋯O hydrogen bond. One of the tert-butyl groups is disordered over two orientations with occupancy ratio of 0.534 (6):0.466 (6). International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588762/ /pubmed/23468727 http://dx.doi.org/10.1107/S1600536812047186 Text en © Baranowska et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Baranowska, Katarzyna
Bulman, Mateusz
Dołęga, Anna
(1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium
title (1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium
title_full (1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium
title_fullStr (1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium
title_full_unstemmed (1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium
title_short (1H-Pyrazole-κN)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) O,S)cadmium
title_sort (1h-pyrazole-κn)bis­(tri-tert-but­oxy­silane­thiol­ato-κ(2) o,s)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588762/
https://www.ncbi.nlm.nih.gov/pubmed/23468727
http://dx.doi.org/10.1107/S1600536812047186
work_keys_str_mv AT baranowskakatarzyna 1hpyrazoleknbistritertbutoxysilanethiolatok2oscadmium
AT bulmanmateusz 1hpyrazoleknbistritertbutoxysilanethiolatok2oscadmium
AT dołegaanna 1hpyrazoleknbistritertbutoxysilanethiolatok2oscadmium

Ejemplares similares