Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate

The title compound, (C(4)H(14)N(2))(2)[Mo(2)O(4)F(6)]·H(2)O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO(3), HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo(2)O(4)F(6)](4−) anionic dimers containing strongly distorted MoO(3)F(...

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Detalles Bibliográficos
Autores principales: Lhoste, J., Hemon-Ribaud, A., Maisonneuve, V., Jobic, S., Bujoli-Doeuff, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588766/
https://www.ncbi.nlm.nih.gov/pubmed/23468731
http://dx.doi.org/10.1107/S1600536812046892
Descripción
Sumario:The title compound, (C(4)H(14)N(2))(2)[Mo(2)O(4)F(6)]·H(2)O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO(3), HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo(2)O(4)F(6)](4−) anionic dimers containing strongly distorted MoO(3)F(3) octa­hedra (with twofold symmetry), diprotonated dab cations and water mol­ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N—H⋯O, N—H⋯F and O—H⋯F inter­actions.

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